Issue

Vol. 13 (2021)

Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries

https://doi.org/10.1007/s40820-021-00700-9
Chiwei Xu
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Zhengwei Yang
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Xikun Zhang
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Maoting Xia
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Huihui Yan
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Jing Li
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Haoxiang Yu
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Liyuan Zhang
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China
Jie Shu
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, People’s Republic of China

Corresponding Author: Jie Shu

shujie@nbu.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 166

Abstract

In the applications of large-scale energy storage, aqueous batteries are considered as rivals for organic batteries due to their environmentally friendly and low-cost nature. However, carrier ions always exhibit huge hydrated radius in aqueous electrolyte, which brings difficulty to find suitable host materials that can achieve highly reversible insertion and extraction of cations. Owing to open three-dimensional rigid framework and facile synthesis, Prussian blue analogues (PBAs) receive the most extensive attention among various host candidates in aqueous system. Herein, a comprehensive review on recent progresses of PBAs in aqueous batteries is presented. Based on the application in different aqueous systems, the relationship between electrochemical behaviors (redox potential, capacity, cycling stability and rate performance) and structural characteristics (preparation method, structure type, particle size, morphology, crystallinity, defect, metal atom in high-spin state and chemical composition) is analyzed and summarized thoroughly. It can be concluded that the required type of PBAs is different for various carrier ions. In particular, the desalination batteries worked with the same mechanism as aqueous batteries are also discussed in detail to introduce the application of PBAs in aqueous systems comprehensively. This report can help the readers to understand the relationship between physical/chemical characteristics and electrochemical properties for PBAs and find a way to fabricate high-performance PBAs in aqueous batteries and desalination batteries.


Highlights:


1 The characteristics of Prussian blue analogues PBAs in different aqueous systems are analyzed.
2 The relationship between structure and performance of PBAs is summarized.
3 The measures to improve electrochemical property of PBAs are proposed.

Keywords

Prussian blue analogues Electrochemistry Cathode Aqueous batteries Desalination batteries
Xu, Chiwei, Zhengwei Yang, Xikun Zhang, Maoting Xia, Huihui Yan, Jing Li, Haoxiang Yu, Liyuan Zhang, and Jie Shu. 2021. “Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries”. Nano-Micro Letters 13 (August):166. https://doi.org/10.1007/s40820-021-00700-9.
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