Ni Flower/MXene-Melamine Foam Derived 3D Magnetic/Conductive Networks for Ultra-Efficient Microwave Absorption and Infrared Stealth
Corresponding Author: Xianhu Liu
Nano-Micro Letters,
Vol. 14 (2022), Article Number: 63
Abstract
The development of multifunctional and efficient electromagnetic wave absorbing materials is a challenging research hotspot. Here, the magnetized Ni flower/MXene hybrids are successfully assembled on the surface of melamine foam (MF) through electrostatic self-assembly and dip-coating adsorption process, realizing the integration of microwave absorption, infrared stealth, and flame retardant. Remarkably, the Ni/MXene-MF achieves a minimum reflection loss (RLmin) of − 62.7 dB with a corresponding effective absorption bandwidth (EAB) of 6.24 GHz at 2 mm and an EAB of 6.88 GHz at 1.8 mm. Strong electromagnetic wave absorption is attributed to the three-dimensional magnetic/conductive networks, which provided excellent impedance matching, dielectric loss, magnetic loss, interface polarization, and multiple attenuations. In addition, the Ni/MXene-MF endows low density, excellent heat insulation, infrared stealth, and flame-retardant functions. This work provided a new development strategy for the design of multifunctional and efficient electromagnetic wave absorbing materials.
Highlights:
1 Ni-MXene/MF foam is synthesized via an electrostatic assembly and dip-coating process.
2 The “micro-capacitor” structure of Ni/MXene and the 3D porous structure of MF endow the foam excellent impedance matching and wave absorption performance.
3 The excellent heat insulation, infrared stealth, and flame-retardant performances are achieved.
Keywords
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Z. Lou, Q. Wang, X. Zhou, U.I. Kara, R.S. Mamtani et al., An angle-insensitive electromagnetic absorber enabling a wideband absorption. J. Mater. Sci. Technol. 113, 33–39 (2022). https://doi.org/10.1016/j.jmst.2021.11.007
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X. Zhang, S. Li, S. Wang, Z. Yin, J. Zhu et al., Self-supported construction of three-dimensional MoS2 hierarchical nanospheres with tunable high-performance microwave absorption in broadband. J. Phys. Chem. C 120(38), 22019–22027 (2016). https://doi.org/10.1021/acs.jpcc.6b06661
H. Sun, R. Che, X. You, Y. Jiang, Z. Yang et al., Cross-stacking aligned carbon-nanotube films to tune microwave absorption frequencies and increase absorption intensities. Adv. Mater. 26(48), 8120–8125 (2014). https://doi.org/10.1002/adma.201403735
Y. Hou, Y. Yang, C. Deng, C. Li, C. Wang, Implications from broadband microwave absorption of metal-modified SiC fiber mats. ACS Appl. Mater. Interfaces 12(28), 31823–31829 (2020). https://doi.org/10.1021/acsami.0c07979
M. Cao, Y. Cai, P. He, J. Shu, W. Cao et al., 2D MXenes: electromagnetic property for microwave absorption and electromagnetic interference shielding. Chem. Eng. J. 359, 1265–1302 (2019). https://doi.org/10.1016/j.cej.2018.11.051
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B. Dai, B. Zhao, X. Xie, T. Su, B. Fan et al., Novel two-dimensional Ti3C2Tx MXenes/nano-carbon sphere hybrids for high-performance microwave absorption. J. Mater. Chem. C 6(21), 5690–5697 (2018). https://doi.org/10.1039/c8tc01404c
L. Liang, R. Yang, G. Han, Y. Feng, B. Zhao et al., Enhanced electromagnetic wave-absorbing performance of magnetic nanoparticles-anchored 2D Ti3C2TxMXene. ACS Appl. Mater. Interfaces 12(2), 2644–2654 (2019). https://doi.org/10.1021/acsami.9b18504
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