Issue

Vol. 13 (2021)

Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries

https://doi.org/10.1007/s40820-021-00726-z
Zhengqing Ye
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China
Ying Jiang
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China
Li Li
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China
Feng Wu
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China
Renjie Chen
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China

Corresponding Author: Renjie Chen

chenrj@bit.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 203

Abstract

Metal–organic framework (MOF)-based materials with high porosity, tunable compositions, diverse structures, and versatile functionalities provide great scope for next-generation rechargeable battery applications. Herein, this review summarizes recent advances in pristine MOFs, MOF composites, MOF derivatives, and MOF composite derivatives for high-performance sodium-ion batteries, potassium-ion batteries, Zn-ion batteries, lithium–sulfur batteries, lithium–oxygen batteries, and Zn–air batteries in which the unique roles of MOFs as electrodes, separators, and even electrolyte are highlighted. Furthermore, through the discussion of MOF-based materials in each battery system, the key principles for controllable synthesis of diverse MOF-based materials and electrochemical performance improvement mechanisms are discussed in detail. Finally, the major challenges and perspectives of MOFs are also proposed for next-generation battery applications.


Highlights:


1 This review summarizes recent progresses in pristine metal–organic frameworks (MOFs), MOF composites, and their derivatives for next-generation rechargeable batteries including lithium–sulfur batteries, lithium–oxygen batteries, sodium-ion batteries, potassium-ion batteries, Zn-ion batteries, and Zn–air batteries.
2 The design strategies for MOF-based materials as the electrode, separator, and electrolyte are outlined and discussed.
3 The challenges and development strategies and of MOF-related materials for battery applications are highlighted.

Keywords

Metal–organic frameworks MOF composites MOF derivatives MOF composite derivatives Batteries
Ye, Zhengqing, Ying Jiang, Li Li, Feng Wu, and Renjie Chen. 2021. “Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries”. Nano-Micro Letters 13 (October):203. https://doi.org/10.1007/s40820-021-00726-z.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. B. Dunn, H. Kamath, J.-M. Tarascon, Electrical energy storage for the grid: a battery of choices. Science 334(6058), 928–935 (2011). https://doi.org/10.1126/science.1212741
  2. M.S. Whittingham, Ultimate limits to intercalation reactions for lithium batteries. Chem. Rev. 114(23), 11414–11443 (2014). https://doi.org/10.1021/cr5003003
  3. P.G. Bruce, S.A. Freunberger, L.J. Hardwick, J.M. Tarascon, Li-O2 and Li-S batteries with high energy storage. Nat. Mater. 11(1), 19–29 (2012). https://doi.org/10.1038/nmat3191
  4. C. Xia, C.Y. Kwok, L.F. Nazar, A high-energy-density lithium-oxygen battery based on a reversible four-electron conversion to lithium oxide. Science 361(6404), 777–781 (2018). https://doi.org/10.1126/science.aas9343
  5. Y. Chen, Z. Wang, X. Li, X. Yao, C. Wang et al., Li metal deposition and stripping in a solid-state battery via coble creep. Nature 578(7794), 251–255 (2020). https://doi.org/10.1038/s41586-020-1972-y
  6. A. Manthiram, Y.Z. Fu, S.H. Chung, C.X. Zu, Y.S. Su, Rechargeable lithium-sulfur batteries. Chem. Rev. 114(23), 11751–11787 (2014). https://doi.org/10.1021/cr500062v
  7. L. Zhang, D. Liu, Z. Muhammad, F. Wan, W. Xie et al., Single nickel atoms on nitrogen-doped graphene enabling enhanced kinetics of lithium–sulfur batteries. Adv. Mater. 31(40), 1903955 (2019). https://doi.org/10.1002/adma.201903955
  8. Z. Ye, Y. Jiang, T. Feng, Z. Wang, L. Li et al., Curbing polysulfide shuttling by synergistic engineering layer composed of supported Sn4P3 nanodots electrocatalyst in lithium-sulfur batteries. Nano Energy 70, 104532 (2020). https://doi.org/10.1016/j.nanoen.2020.104532
  9. J.-S. Lee, S. Tai Kim, R. Cao, N.-S. Choi, M. Liu et al., Metal–air batteries with high energy density: Li–air versus Zn–air. Adv. Energy Mater. 1(1), 34–50 (2011). https://doi.org/10.1002/aenm.201000010
  10. L. Jiang, Y. Lu, C. Zhao, L. Liu, J. Zhang et al., Building aqueous K-ion batteries for energy storage. Nat. Energy 4(6), 495–503 (2019). https://doi.org/10.1038/s41560-019-0388-0
  11. F. Wu, Y. Jiang, Z. Ye, Y. Huang, Z. Wang et al., A 3D flower-like VO2/Mxene hybrid architecture with superior anode performance for sodium ion batteries. J. Mater. Chem. A 7(3), 1315–1322 (2019). https://doi.org/10.1039/c8ta11419f
  12. H.J. Huang, R. Xu, Y.Z. Feng, S.F. Zeng, Y. Jiang et al., Sodium/potassium-ion batteries: boosting the rate capability and cycle life by combining morphology, defect and structure engineering. Adv. Mater. 32(8), 1904320 (2020). https://doi.org/10.1002/adma.201904320
  13. Y.-P. Deng, R. Liang, G. Jiang, Y. Jiang, A. Yu et al., The current state of aqueous Zn-based rechargeable batteries. ACS Energy Lett. 5(5), 1665–1675 (2020). https://doi.org/10.1021/acsenergylett.0c00502
  14. L.E. Blanc, D. Kundu, L.F. Nazar, Scientific challenges for the implementation of Zn-ion batteries. Joule 4(4), 771–799 (2020). https://doi.org/10.1016/j.joule.2020.03.002
  15. H. Jia, Z. Wang, B. Tawiah, Y. Wang, C.-Y. Chan et al., Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries. Nano Energy 70, 104523 (2020). https://doi.org/10.1016/j.nanoen.2020.104523
  16. H. Zheng, Y. Zhang, L. Liu, W. Wan, P. Guo et al., One-pot synthesis of metal organic frameworks with encapsulated target molecules and their applications for controlled drug delivery. J. Am. Chem. Soc. 138(3), 962–968 (2016). https://doi.org/10.1021/jacs.5b11720
  17. M.H. Teplensky, M. Fantham, C. Poudel, C. Hockings, M. Lu et al., A highly porous metal-organic framework system to deliver payloads for gene knockdown. Chem 5(11), 2926–2941 (2019). https://doi.org/10.1016/j.chempr.2019.08.015
  18. S. Yuan, X. Sun, J. Pang, C. Lollar, J.-S. Qin et al., PCN-250 under pressure: sequential phase transformation and the implications for MOF densification. Joule 1(4), 806–815 (2017). https://doi.org/10.1016/j.joule.2017.09.001
  19. Y. Liu, G. Liu, C. Zhang, W. Qiu, S. Yi et al., Enhanced CO2/CH4 separation performance of a mixed matrix membrane based on tailored MOF-polymer formulations. Adv. Sci. 5(9), 1800982 (2018). https://doi.org/10.1002/advs.201800982
  20. C.-C. Hou, Q. Xu, Metal-organic frameworks for energy. Adv. Energy Mater. 9(23), 1801307 (2018). https://doi.org/10.1002/aenm.201801307
  21. Z. Li, X. Ge, C. Li, S. Dong, R. Tang et al., Rational microstructure design on metal–organic framework composites for better electrochemical performances: design principle, synthetic strategy, and promotion mechanism. Small Methods 4(3), 1900756 (2020). https://doi.org/10.1002/smtd.201900756
  22. J. Haoqing, L. Xiao-Chen, W. Yushan, S. Yufei, G. Xuan et al., Metal–organic frameworks for high charge–discharge rates in lithium–sulfur batteries. Angew. Chem. Int. Ed. 57(15), 3916–3921 (2018). https://doi.org/10.1002/anie.201712872
  23. S. Kitagawa, R. Kitaura, S.-I. Noro, Functional porous coordination polymers. Angew. Chem. Int. Ed. 43(18), 2334–2375 (2004). https://doi.org/10.1002/anie.200300610
  24. J. Meng, X. Liu, C. Niu, Q. Pang, J. Li et al., Advances in metal-organic framework coatings: versatile synthesis and broad applications. Chem. Soc. Rev. 49, 3142–3186 (2020). https://doi.org/10.1039/c9cs00806c
  25. S.H. Ahn, A. Manthiram, Cobalt phosphide coupled with heteroatom-doped nanocarbon hybrid electroctalysts for efficient, long-life rechargeable zinc–air batteries. Small 13(40), 1702068 (2017). https://doi.org/10.1002/smll.201702068
  26. S. Dang, Q.-L. Zhu, Q. Xu, Nanomaterials derived from metal–organic frameworks. Nat. Rev. Mater. 3(1), 17075 (2017). https://doi.org/10.1038/natrevmats.2017.75
  27. Y. Li, R. Cao, L. Li, X. Tang, T. Chu et al., Simultaneously integrating single atomic cobalt sites and Co9S8 nanoparticles into hollow carbon nanotubes as trifunctional electrocatalysts for Zn–air batteries to drive water splitting. Small 16(10), 1906735 (2020). https://doi.org/10.1002/smll.201906735
  28. R. Demir-Cakan, M. Morcrette, F. Nouar, C. Davoisne, T. Devic et al., Cathode composites for Li–S batteries via the use of oxygenated porous architectures. J. Am. Chem. Soc. 133(40), 16154–16160 (2011). https://doi.org/10.1021/ja2062659
  29. J.M. Zheng, J. Tian, D.X. Wu, M. Gu, W. Xu et al., Lewis acid-base interactions between polysulfides and metal organic framework in lithium sulfur batteries. Nano Lett. 14(5), 2345–2352 (2014). https://doi.org/10.1021/nl404721h
  30. Y. Zang, F. Pei, J. Huang, Z. Fu, G. Xu et al., Large-area preparation of crack-free crystalline microporous conductive membrane to upgrade high energy lithium–sulfur batteries. Adv. Energy Mater. 8(31), 1802052 (2018). https://doi.org/10.1002/aenm.201802052
  31. M. Tian, F. Pei, M. Yao, Z. Fu, L. Lin et al., Ultrathin MOF nanosheet assembled highly oriented microporous membrane as an interlayer for lithium-sulfur batteries. Energy Storage Mater. 21, 14–21 (2019). https://doi.org/10.1016/j.ensm.2018.12.016
  32. Y. He, Z. Chang, S. Wu, Y. Qiao, S. Bai et al., Simultaneously inhibiting lithium dendrites growth and polysulfides shuttle by a flexible MOF-based membrane in Li-S batteries. Adv. Energy Mater. 8(34), 1802130 (2018). https://doi.org/10.1002/aenm.201802130
  33. J. Qian, Y. Li, M. Zhang, R. Luo, F. Wang et al., Protecting lithium/sodium metal anode with metal-organic framework based compact and robust shield. Nano Energy 60, 866–874 (2019). https://doi.org/10.1016/j.nanoen.2019.04.030
  34. M. Rana, H.A. Al-Fayaad, B. Luo, T. Lin, L. Ran et al., Oriented nanoporous MOFs to mitigate polysulfides migration in lithium-sulfur batteries. Nano Energy 75, 105009 (2020). https://doi.org/10.1016/j.nanoen.2020.105009
  35. H. Zhang, W. Zhao, M. Zou, Y. Wang, Y. Chen et al., 3D, mutually embedded MOF@carbon nanotube hybrid networks for high-performance lithium-sulfur batteries. Adv. Energy Mater. 8(19), 1800013 (2018). https://doi.org/10.1002/aenm.201800013
  36. S.Y. Bai, X.Z. Liu, K. Zhu, S.C. Wu, H.S. Zhou, Metal-organic framework-based separator for lithium-sulfur batteries. Nat. Energy 1, 6 (2016). https://doi.org/10.1038/nenergy.2016.94
  37. Y.Y. Mao, G.R. Li, Y. Guo, Z.P. Li, C.D. Liang et al., Foldable interpenetrated metal-organic frameworks/carbon nanotubes thin film for lithium-sulfur batteries. Nat. Commun. 8, 8 (2017). https://doi.org/10.1038/ncomms14628
  38. A.E. Baumann, J.R. Downing, D.A. Burns, M.C. Hersam, V.S. Thoi, Graphene–metal–organic framework composite sulfur electrodes for Li–S batteries with high volumetric capacity. ACS Appl. Mater. Interfaces 12(33), 37173–37181 (2020). https://doi.org/10.1021/acsami.0c09622
  39. C. Wu, S. Gu, Q. Zhang, Y. Bai, M. Li et al., Electrochemically activated spinel manganese oxide for rechargeable aqueous aluminum battery. Nat. Commun. 10(1), 73 (2019). https://doi.org/10.1038/s41467-018-07980-7
  40. B. Liu, M. Taheri, J.F. Torres, Z. Fusco, T. Lu et al., Janus conductive/insulating microporous ion-sieving membranes for stable Li-S batteries. ACS Nano 14(10), 13852–13864 (2020). https://doi.org/10.1021/acsnano.0c06221
  41. B. Liu, R. Bo, M. Taheri, I. Di Bernardo, N. Motta et al., Metal–organic frameworks/conducting polymer hydrogel integrated three-dimensional free-standing monoliths as ultrahigh loading Li–S battery electrodes. Nano Lett. 19(7), 4391–4399 (2019). https://doi.org/10.1021/acs.nanolett.9b01033
  42. P. Chiochan, X. Yu, M. Sawangphruk, A. Manthiram, A metal organic framework derived solid electrolyte for lithium–sulfur batteries. Adv. Energy Mater. 10(27), 2001285 (2020). https://doi.org/10.1002/aenm.202001285
  43. B. Liu, V.S. Thoi, Improving charge transfer in metal–organic frameworks through open site functionalization and porosity selection for Li–S batteries. Chem. Mater. 32(19), 8450–8459 (2020). https://doi.org/10.1021/acs.chemmater.0c02438
  44. A.E. Baumann, X. Han, M.M. Butala, V.S. Thoi, Lithium thiophosphate functionalized zirconium MOFs for Li-S batteries with enhanced rate capabilities. J. Am. Chem. Soc. 141(44), 17891–17899 (2019). https://doi.org/10.1021/jacs.9b09538
  45. Z. Chang, Y. Qiao, J. Wang, H. Deng, P. He et al., Fabricating better metal-organic frameworks separators for Li-S batteries: pore sizes effects inspired channel modification strategy. Energy Storage Mater. 25, 164–171 (2020). https://doi.org/10.1016/j.ensm.2019.10.018
  46. Z. Wang, W. Huang, J. Hua, Y. Wang, H. Yi et al., An anionic-mof-based bifunctional separator for regulating lithium deposition and suppressing polysulfides shuttle in Li–S batteries. Small Methods 4(7), 2000082 (2020). https://doi.org/10.1002/smtd.202000082
  47. Y. Li, S. Lin, D. Wang, T. Gao, J. Song et al., Single atom array mimic on ultrathin MOF nanosheets boosts the safety and life of lithium–sulfur batteries. Adv. Mater. 32(8), 1906722 (2020). https://doi.org/10.1002/adma.201906722
  48. G.K. Gao, Y.R. Wang, S.B. Wang, R.X. Yang, Y. Chen et al., Stepped channels integrated lithium-sulfur separator via photoinduced multidimensional fabrication of metal-organic frameworks. Angew. Chem. Int. Ed. 60(18), 10147–10154 (2021). https://doi.org/10.1002/anie.202016608
  49. D.-D. Han, Z.-Y. Wang, G.-L. Pan, X.-P. Gao, Metal–organic-framework-based gel polymer electrolyte with immobilized anions to stabilize a lithium anode for a quasi-solid-state lithium–sulfur battery. ACS Appl. Mater. Interfaces 11(20), 18427–18435 (2019). https://doi.org/10.1021/acsami.9b03682
  50. Y.J. Li, J.M. Fan, M.S. Zheng, Q.F. Dong, A novel synergistic composite with multi-functional effects for high-performance Li-S batteries. Energy Environ. Sci. 9(6), 1998–2004 (2016). https://doi.org/10.1039/c6ee00104a
  51. Y. Wu, X. Zhu, P. Li, T. Zhang, M. Li et al., Ultradispersed WxC nanoparticles enable fast polysulfide interconversion for high-performance Li-S batteries. Nano Energy 59, 636–643 (2019). https://doi.org/10.1016/j.nanoen.2019.03.015
  52. G. Chen, Y. Li, W. Zhong, F. Zheng, J. Hu et al., MOFs-derived porous Mo2C–C nano-octahedrons enable high-performance lithium–sulfur batteries. Energy Storage Mater. 25, 547–554 (2020). https://doi.org/10.1016/j.ensm.2019.09.028
  53. S.D. Seo, D. Park, S. Park, D.W. Kim, “Brain-coral-like” mesoporous hollow CoS2@N-doped graphitic carbon nanoshells as efficient sulfur reservoirs for lithium–sulfur batteries. Adv. Funct. Mater. 29(38), 1903712 (2019). https://doi.org/10.1002/adfm.201903712
  54. Y.X. Tian, H.W. Huang, G.X. Liu, R. Bi, L. Zhang, Metal-organic framework derived yolk-shell NiS2/carbon spheres for lithium-sulfur batteries with enhanced polysulfide redox kinetics. Chem. Commun. 55(22), 3243–3246 (2019). https://doi.org/10.1039/c9cc00486f
  55. Z. Sun, S. Vijay, H.H. Heenen, A.Y.S. Eng, W. Tu et al., Catalytic polysulfide conversion and physiochemical confinement for lithium–sulfur batteries. Adv. Energy Mater. 10(22), 1904010 (2020). https://doi.org/10.1002/aenm.201904010
  56. Z. Ye, Y. Jiang, J. Qian, W. Li, T. Feng et al., Exceptional adsorption and catalysis effects of hollow polyhedra/carbon nanotube confined CoP nanoparticles superstructures for enhanced lithium–sulfur batteries. Nano Energy 64, 103965 (2019). https://doi.org/10.1016/j.nanoen.2019.103965
  57. S.-D. Seo, C. Choi, D. Park, D.-Y. Lee, S. Park et al., Metal-organic-framework-derived 3D crumpled carbon nanosheets with self-assembled CoxSy nanocatalysts as an interlayer for lithium-sulfur batteries. Chem. Eng. J. 400, 125959 (2020). https://doi.org/10.1016/j.cej.2020.125959
  58. J. Cai, Y. Song, X. Chen, Z. Sun, Y. Yi et al., MOF-derived conductive carbon nitrides for separator-modified Li-S batteries and flexible supercapacitors. J. Mater. Chem. A 8(4), 1757–1766 (2020). https://doi.org/10.1039/C9TA11958B
  59. J. He, Y. Chen, A. Manthiram, Vertical Co9S8 hollow nanowall arrays grown on celgard separator as a multifunctional polysulfide barrier for high-performance Li-S batteries. Energy Environ. Sci. 11(9), 2560–2568 (2018). https://doi.org/10.1039/C8EE00893K
  60. X.-J. Hong, C.-L. Song, Z.-M. Wu, Z.-H. Li, Y.-P. Cai et al., Sulfophilic and lithophilic sites in bimetal nickel-zinc carbide with fast conversion of polysulfides for high-rate Li-S battery. Chem. Eng. J. 404, 126566 (2021). https://doi.org/10.1016/j.cej.2020.126566
  61. Y. Zhong, F. Lin, M. Wang, Y. Zhang, Q. Ma et al., Metal organic framework derivative improving lithium metal anode cycling. Adv. Funct. Mater. 30(10), 1907579 (2020). https://doi.org/10.1002/adfm.201907579
  62. K. Chen, Z. Sun, R. Fang, Y. Shi, H.-M. Cheng et al., Metal-organic frameworks (MOFs)-derived nitrogen-doped porous carbon anchored on graphene with multifunctional effects for lithium-sulfur batteries. Adv. Funct. Mater. 28(38), 1707592 (2018). https://doi.org/10.1002/adfm.201707592
  63. D. Fang, Y. Wang, X. Liu, J. Yu, C. Qian et al., Spider-web-inspired nanocomposite-modified separator: Structural and chemical cooperativity inhibiting the shuttle effect in Li-S batteries. ACS Nano 13(2), 1563–1573 (2019). https://doi.org/10.1021/acsnano.8b07491
  64. R. Wang, J. Yang, X. Chen, Y. Zhao, W. Zhao et al., Highly dispersed cobalt clusters in nitrogen-doped porous carbon enable multiple effects for high-performance Li–S battery. Adv. Energy Mater. 10(9), 1903550 (2020). https://doi.org/10.1002/aenm.201903550
  65. W. Cai, G. Li, D. Luo, G. Xiao, S. Zhu et al., The dual-play of 3D conductive scaffold embedded with Co, N codoped hollow polyhedra toward high-performance Li–S full cell. Adv. Energy Mater. 8(34), 1802561 (2018). https://doi.org/10.1002/aenm.201802561
  66. W. Li, J. Qian, T. Zhao, Y. Ye, Y. Xing et al., Boosting high-rate Li–S batteries by an MOF-derived catalytic electrode with a layer-by-layer structure. Adv. Sci. 6(16), 1802362 (2019). https://doi.org/10.1002/advs.201802362
  67. Z. Wang, J. Shen, J. Liu, X. Xu, Z. Liu et al., Self-supported and flexible sulfur cathode enabled via synergistic confinement for high-energy-density lithium-sulfur batteries. Adv. Mater. 31(33), 1902228 (2019). https://doi.org/10.1002/adma.201902228
  68. L. Zhang, Y. Liu, Z. Zhao, P. Jiang, T. Zhang et al., Enhanced polysulfide regulation via porous catalytic V2O3/V8C7 heterostructures derived from metal-organic frameworks toward high-performance Li-S batteries. ACS Nano 14(7), 8495–8507 (2020). https://doi.org/10.1021/acsnano.0c02762
  69. X. Yang, X. Gao, Q. Sun, S.P. Jand, Y. Yu et al., Promoting the transformation of Li2S2 to Li2S: significantly increasing utilization of active materials for high-sulfur-loading Li-S batteries. Adv. Mater. 31(25), 1901220 (2019). https://doi.org/10.1002/adma.201901220
  70. Z. Ye, Y. Jiang, L. Li, F. Wu, R. Chen, A high-efficiency CoSe electrocatalyst with hierarchical porous polyhedron nanoarchitecture for accelerating polysulfides conversion in Li–S batteries. Adv. Mater. 32(32), 2002168 (2020). https://doi.org/10.1002/adma.202002168
  71. Q. Wu, Z. Yao, X. Zhou, J. Xu, F. Cao et al., Built-in catalysis in confined nanoreactors for high-loading Li-S batteries. ACS Nano 14(3), 3365–3377 (2020). https://doi.org/10.1021/acsnano.9b09231
  72. B. Fei, C. Zhang, D. Cai, J. Zheng, Q. Chen et al., Hierarchical nanoreactor with multiple adsorption and catalytic sites for robust lithium-sulfur batteries. ACS Nano 15(4), 6849–6860 (2021). https://doi.org/10.1021/acsnano.0c10603
  73. Z. Ye, Y. Jiang, L. Li, F. Wu, R. Chen, Self-assembly of 0D–2D heterostructure electrocatalyst from MOF and MXene for boosted lithium polysulfide conversion reaction. Adv. Mater. 33(33), 2101204 (2021). https://doi.org/10.1002/adma.202101204
  74. R. Liu, Z. Liu, W. Liu, Y. Liu, X. Lin et al., TiO2 and Co nanoparticle-decorated carbon polyhedra as efficient sulfur host for high-performance lithium-sulfur batteries. Small 15(29), 1804533 (2019). https://doi.org/10.1002/smll.201804533
  75. S. Chen, J. Luo, N. Li, X. Han, J. Wang et al., Multifunctional LDH/Co9S8 heterostructure nanocages as high-performance lithium–sulfur battery cathodes with ultralong lifespan. Energy Storage Mater. 30, 187–195 (2020). https://doi.org/10.1016/j.ensm.2020.05.002
  76. J. Zhang, G. Li, Y. Zhang, W. Zhang, X. Wang et al., Vertically rooting multifunctional tentacles on carbon scaffold as efficient polysulfide barrier toward superior lithium-sulfur batteries. Nano Energy 64, 103905 (2019). https://doi.org/10.1016/j.nanoen.2019.103905
  77. H. Li, Y. Wang, H. Chen, B. Niu, W. Zhang et al., Synergistic mediation of polysulfide immobilization and conversion by a catalytic and dual-adsorptive system for high performance lithium-sulfur batteries. Chem. Eng. J. 406, 126802 (2021). https://doi.org/10.1016/j.cej.2020.126802
  78. B. Guan, Y. Zhang, L. Fan, X. Wu, M. Wang et al., Blocking polysulfide with Co2B@CNT via “synergetic adsorptive effect” toward ultrahigh-rate capability and robust lithium–sulfur battery. ACS Nano 13(6), 6742–6750 (2019). https://doi.org/10.1021/acsnano.9b01329
  79. H. Shi, X. Ren, J. Lu, C. Dong, J. Liu et al., Dual-functional atomic zinc decorated hollow carbon nanoreactors for kinetically accelerated polysulfides conversion and dendrite free lithium sulfur batteries. Adv. Energy Mater. 10(39), 2002271 (2020). https://doi.org/10.1002/aenm.202002271
  80. S.H. Liu, J. Li, X. Yan, Q.F. Su, Y.H. Lu et al., Superhierarchical cobalt-embedded nitrogen-doped porous carbon nanosheets as two-in-one hosts for high-performance lithium-sulfur batteries. Adv. Mater. 30(12), 9 (2018). https://doi.org/10.1002/adma.201706895
  81. D. Wu, Z. Guo, X. Yin, Q. Pang, B. Tu et al., Metal-organic frameworks as cathode materials for Li-O2 batteries. Adv. Mater. 26(20), 3258 (2014). https://doi.org/10.1002/adma.201305492
  82. S.H. Kim, Y.J. Lee, D.H. Kim, Y.J. Lee, Bimetallic metal–organic frameworks as efficient cathode catalysts for Li–O2 batteries. ACS Appl. Mater. Interfaces 10(1), 660–667 (2018). https://doi.org/10.1021/acsami.7b15499
  83. S. Yuan, J.L. Bao, J. Wei, Y. Xia, D.G. Truhlar et al., A versatile single-ion electrolyte with a grotthuss-like Li conduction mechanism for dendrite-free Li metal batteries. Energy Environ. Sci. 12(9), 2741–2750 (2019). https://doi.org/10.1039/c9ee01473j
  84. X. Zhang, P. Dong, J.-I. Lee, J.T. Gray, Y.-H. Cha et al., Enhanced cycling performance of rechargeable Li-O2 batteries via LiOH formation and decomposition using high-performance MOF-74@CNTs hybrid catalysts. Energy Storage Mater. 17, 167–177 (2019). https://doi.org/10.1016/j.ensm.2018.11.014
  85. W.H. Choi, B.C. Moon, D.G. Park, J.W. Choi, K.H. Kim et al., Autogenous production and stabilization of highly loaded sub-nanometric particles within multishell hollow metal–organic frameworks and their utilization for high performance in Li–O2 batteries. Adv. Sci. 7(9), 2000283 (2020). https://doi.org/10.1002/advs.202000283
  86. L. Cao, F. Lv, Y. Liu, W. Wang, Y. Huo et al., A high performance O2 selective membrane based on CAU-L-NH2@polydopamine and the pmma polymer for Li–air batteries. Chem. Commun. 51(21), 4364–4367 (2015). https://doi.org/10.1039/C4CC09281C
  87. Y. Qiao, Y. He, S. Wu, K. Jiang, X. Li et al., MOF-based separator in an Li-O2 battery: an effective strategy to restrain the shuttling of dual redox mediators. ACS Energy Lett. 3(2), 463–468 (2018). https://doi.org/10.1021/acsenergylett.8b00014
  88. Q. Li, P. Xu, W. Gao, S. Ma, G. Zhang et al., Graphene/graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O2 batteries. Adv. Mater. 26(9), 1378–1386 (2014). https://doi.org/10.1002/adma.201304218
  89. G. Tan, L. Chong, R. Amine, J. Lu, C. Liu et al., Toward highly efficient electrocatalyst for Li-O2 batteries using biphasic N-doping cobalt@graphene multiple-capsule heterostructures. Nano Lett. 17(5), 2959–2966 (2017). https://doi.org/10.1021/acs.nanolett.7b00207
  90. J. Tang, S. Wu, T. Wang, H. Gong, H. Zhang et al., Cage-type highly graphitic porous carbon–Co3O4 polyhedron as the cathode of lithium–oxygen batteries. ACS Appl. Mater. Interfaces 8(4), 2796–2804 (2016). https://doi.org/10.1021/acsami.5b11252
  91. H. Gong, H. Xue, X. Lu, B. Gao, T. Wang et al., All solid-state lithium-oxygen batteries with MOF-derived nickel cobaltate nanoflake arrays as high-performance oxygen cathodes. Chem. Commun. 55(72), 10689–10692 (2019). https://doi.org/10.1039/c9cc05685h
  92. W. Yin, Y. Shen, F. Zou, X. Hu, B. Chi et al., Metal-organic framework derived ZnO/ZnFe2O4/C nanocages as stable cathode material for reversible lithium-oxygen batteries. ACS Appl. Mater. Interfaces 7(8), 4947–4954 (2015). https://doi.org/10.1021/am509143t
  93. Y. Dou, R. Lian, Y. Zhang, Y. Zhao, G. Chen et al., Co9S8@carbon porous nanocages derived from a metal–organic framework: a highly efficient bifunctional catalyst for aprotic Li–O2 batteries. J. Mater. Chem. A 6(18), 8595–8603 (2018). https://doi.org/10.1039/C8TA01913D
  94. H. Wang, F.-X. Yin, N. Liu, R.-H. Kou, X.-B. He et al., Engineering Fe-Fe3C@Fe-N-C active sites and hybrid structures from dual metal-organic frameworks for oxygen reduction reaction in H2O2 fuel cell and Li-O2 battery. Adv. Funct. Mater. 29(23), 1901531 (2019). https://doi.org/10.1002/adfm.201901531
  95. P. Wang, Y. Ren, R. Wang, P. Zhang, M. Ding et al., Atomically dispersed cobalt catalyst anchored on nitrogen-doped carbon nanosheets for lithium-oxygen batteries. Nat. Commun. 11(1), 1576 (2020). https://doi.org/10.1038/s41467-020-15416-4
  96. P. Hien Thi Thu, Y. Kim, Y.-J. Kim, J.-W. Lee, M.-S. Park, Robust design of dual-phasic carbon cathode for lithium-oxygen batteries. Adv. Funct. Mater. 29(31), 1902915 (2019). https://doi.org/10.1002/adfm.201902915
  97. W.M. Zhang, X.Y. Yao, S.N. Zhou, X.W. Li, L. Li et al., ZIF-8/ZIF-67-derived Co-Nx-embedded 1D porous carbon nanofibers with graphitic carbon-encased Co nanoparticles as an efficient bifunctional electrocatalyst. Small 14(24), 1800423 (2018). https://doi.org/10.1002/smll.201800423
  98. Z. Lyu, G.J.H. Lim, R. Guo, Z. Kou, T. Wang et al., 3D-printed MOF-derived hierarchically porous frameworks for practical high-energy density Li-O2 batteries. Adv. Funct. Mater. 29(1), 1806658 (2019). https://doi.org/10.1002/adfm.201806658
  99. X. Hu, G. Luo, Q. Zhao, D. Wu, T. Yang et al., Ru single atoms on N-doped carbon by spatial confinement and ionic substitution strategies for high-performance Li-O2 batteries. J. Am. Chem. Soc. 142(39), 16776–16786 (2020). https://doi.org/10.1021/jacs.0c07317
  100. Y. Lu, L. Wang, J. Cheng, J.B. Goodenough, Prussian blue: A new framework of electrode materials for sodium batteries. Chem. Commun. 48(52), 6544–6546 (2012). https://doi.org/10.1039/C2CC31777J
  101. L. Wang, Y. Lu, J. Liu, M. Xu, J. Cheng et al., A superior low-cost cathode for a Na-ion battery. Angew. Chem. In. Ed. 52(7), 1964–1967 (2013). https://doi.org/10.1002/anie.201206854
  102. Y. You, X.-L. Wu, Y.-X. Yin, Y.-G. Guo, High-quality prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ. Sci. 7(5), 1643–1647 (2014). https://doi.org/10.1039/C3EE44004D
  103. J. Song, L. Wang, Y. Lu, J. Liu, B. Guo et al., Removal of interstitial H2O in hexacyanometallates for a superior cathode of a sodium-ion battery. J. Am. Chem. Soc. 137(7), 2658–2664 (2015). https://doi.org/10.1021/ja512383b
  104. X. Wu, W. Deng, J. Qian, Y. Cao, X. Ai et al., Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries. J. Mater. Chem. A 1(35), 10130–10134 (2013). https://doi.org/10.1039/C3TA12036H
  105. Y. Ma, Y. Ma, S.L. Dreyer, Q. Wang, K. Wang et al., High-entropy metal–organic frameworks for highly reversible sodium storage. Adv. Mater. (2021). https://doi.org/10.1002/adma.202101342
  106. H.-W. Lee, R.Y. Wang, M. Pasta, S. Woo Lee, N. Liu et al., Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries. Nat. Commun. 5(1), 5280 (2014). https://doi.org/10.1038/ncomms6280
  107. Y. Yue, A.J. Binder, B. Guo, Z. Zhang, Z.A. Qiao et al., Mesoporous prussian blue analogues: template-free synthesis and sodium-ion battery applications. Angew. Chem. Int. Ed. 53(12), 3134–3137 (2014). https://doi.org/10.1002/anie.201310679
  108. Y. Tang, W. Li, P. Feng, M. Zhou, K. Wang et al., High-performance manganese hexacyanoferrate with cubic structure as superior cathode material for sodium-ion batteries. Adv. Funct. Mater. 30(10), 1908754 (2020). https://doi.org/10.1002/adfm.201908754
  109. C. Li, Q. Yang, M. Shen, J.Y. Ma, B.W. Hu, The electrochemical Na intercalation/extraction mechanism of ultrathin cobalt(ii) terephthalate-based MOF nanosheets revealed by synchrotron X-ray absorption spectroscopy. Energy Storage Mater. 14, 82–89 (2018). https://doi.org/10.1016/j.ensm.2018.02.021
  110. J. Park, M. Lee, D.W. Feng, Z.H. Huang, A.C. Hinckley et al., Stabilization of hexaaminobenzene in a 2D conductive metal-organic framework for high power sodium storage. J. Am. Chem. Soc. 140(32), 10315–10323 (2018). https://doi.org/10.1021/jacs.8b06020
  111. Y. Liu, X. Zhao, C. Fang, Z. Ye, Y.-B. He et al., Activating aromatic rings as Na-ion storage sites to achieve high capacity. Chem 4(10), 2463–2478 (2018). https://doi.org/10.1016/j.chempr.2018.08.015
  112. Y. Jiang, S. Yu, B. Wang, Y. Li, W. Sun et al., Prussian blue@C composite as an ultrahigh-rate and long-life sodium-ion battery cathode. Adv. Funct. Mater. 26(29), 5315–5321 (2016). https://doi.org/10.1002/adfm.201600747
  113. Y. You, H.-R. Yao, S. Xin, Y.-X. Yin, T.-T. Zuo et al., Subzero-temperature cathode for a sodium-ion battery. Adv. Mater. 28(33), 7243–7248 (2016). https://doi.org/10.1002/adma.201600846
  114. J. Luo, S. Sun, J. Peng, B. Liu, Y. Huang et al., Graphene-roll-wrapped prussian blue nanospheres as a high-performance binder-free cathode for sodium-ion batteries. ACS Appl. Mater. Interfaces 9(30), 25317–25322 (2017). https://doi.org/10.1021/acsami.7b06334
  115. Y. Huang, C. Fang, R. Zeng, Y. Liu, W. Zhang et al., In situ-formed hierarchical metal–organic flexible cathode for high-energy sodium-ion batteries. Chemsuschem 10(23), 4704–4708 (2017). https://doi.org/10.1002/cssc.201701484
  116. Y. Mao, Y. Chen, J. Qin, C. Shi, E. Liu et al., Capacitance controlled, hierarchical porous 3D ultra-thin carbon networks reinforced prussian blue for high performance Na-ion battery cathode. Nano Energy 58, 192–201 (2019). https://doi.org/10.1016/j.nanoen.2019.01.048
  117. Y. Tang, W. Zhang, L. Xue, X. Ding, T. Wang et al., Polypyrrole-promoted superior cyclability and rate capability of NaxFe[Fe(CN)6] cathodes for sodium-ion batteries. J. Mater. Chem. A 4(16), 6036–6041 (2016). https://doi.org/10.1039/C6TA00876C
  118. W.-J. Li, S.-L. Chou, J.-Z. Wang, J.-L. Wang, Q.-F. Gu et al., Multifunctional conducing polymer coated Na1+xMnFe(CN)6 cathode for sodium-ion batteries with superior performance via a facile and one-step chemistry approach. Nano Energy 13, 200–207 (2015). https://doi.org/10.1016/j.nanoen.2015.02.019
  119. Q. Qu, J. Yun, Z. Wan, H. Zheng, T. Gao et al., MOF-derived microporous carbon as a better choice for Na-ion batteries than mesoporous CMK-3. RSC Adv. 4(110), 64692–64697 (2014). https://doi.org/10.1039/c4ra11009a
  120. X. Shi, Y. Chen, Y. Lai, K. Zhang, J. Li et al., Metal organic frameworks templated sulfur-doped mesoporous carbons as anode materials for advanced sodium ion batteries. Carbon 123, 250–258 (2017). https://doi.org/10.1016/j.carbon.2017.07.056
  121. S. Liu, J. Zhou, H. Song, 2D Zn-hexamine coordination frameworks and their derived N-rich porous carbon nanosheets for ultrafast sodium storage. Adv. Energy Mater. 8(22), 1800569 (2018). https://doi.org/10.1002/aenm.201800569
  122. Y. Xie, J. Hu, Z. Han, T. Wang, J. Zheng et al., Encapsulating sodium deposition into carbon rhombic dodecahedron guided by sodiophilic sites for dendrite-free Na metal batteries. Energy Storage Mater. 30, 1–8 (2020). https://doi.org/10.1016/j.ensm.2020.05.008
  123. M.Q. Zhu, S.M. Li, B. Li, Y.J. Gong, Z.G. Du et al., Homogeneous guiding deposition of sodium through main group II metals toward dendrite-free sodium anodes. Sci. Adv. 5(4), 8 (2019). https://doi.org/10.1126/sciadv.aau6264
  124. H. Xu, Y. Liu, T. Qiang, L. Qin, J. Chen et al., Boosting sodium storage properties of titanium dioxide by a multiscale design based on MOF-derived strategy. Energy Storage Mater. 17, 126–135 (2019). https://doi.org/10.1016/j.ensm.2018.07.023
  125. H.-H. Li, Z.-Y. Li, X.-L. Wu, L.-L. Zhang, C.-Y. Fan et al., Shale-like Co3O4 for high performance lithium/sodium ion batteries. J. Mater. Chem. A 4(21), 8242–8248 (2016). https://doi.org/10.1039/C6TA02417C
  126. Y. Cai, G. Fang, J. Zhou, S. Liu, Z. Luo et al., Metal-organic framework-derived porous shuttle-like vanadium oxides for sodium-ion battery application. Nano Res. 11(1), 449–463 (2018). https://doi.org/10.1007/s12274-017-1653-9
  127. S. Fan, S. Huang, Y. Chen, Y. Shang, Y. Wang et al., Construction of complex NiS multi-shelled hollow structures with enhanced sodium storage. Energy Storage Mater. 23, 17–24 (2019). https://doi.org/10.1016/j.ensm.2019.05.043
  128. X. Xu, J. Liu, J. Liu, L. Ouyang, R. Hu et al., A general metal-organic framework (MOF)-derived selenidation strategy for in situ carbon-encapsulated metal selenides as high-rate anodes for Na-ion batteries. Adv. Funct. Mater. 28(16), 1707573 (2018). https://doi.org/10.1002/adfm.201707573
  129. N. Shi, B. Xi, M. Huang, X. Ma, H. Li et al., Hierarchical octahedra constructed by Cu2S/MoS2 subsetcarbon framework with enhanced sodium storage. Small 16(23), 2000952 (2020). https://doi.org/10.1002/smll.202000952
  130. X. Wang, Y. Chen, Y.J. Fang, J.T. Zhang, S.Y. Gao et al., Synthesis of cobalt sulfide multi-shelled nanoboxes with precisely controlled two to five shells for sodium-ion batteries. Angew. Chem. Int. Ed. 58(9), 2675–2679 (2019). https://doi.org/10.1002/anie.201812387
  131. Y. Zhang, Q. Su, W. Xu, G. Cao, Y. Wang et al., A confined replacement synthesis of bismuth nanodots in MOF derived carbon arrays as binder-free anodes for sodium-ion batteries. Adv. Sci. 6(16), 1900162 (2019). https://doi.org/10.1002/advs.201900162
  132. W. Zhang, W. Yan, H. Jiang, C. Wang, Y. Zhou et al., Uniform Bi–Sb alloy nanoparticles synthesized from MOFs by laser metallurgy for sodium-ion batteries. ACS Sustain. Chem. Eng. 8(1), 335–342 (2019). https://doi.org/10.1021/acssuschemeng.9b05474
  133. X. Hu, X. Liu, K. Chen, G. Wang, H. Wang, Core–shell mof-derived N-doped yolk–shell carbon nanocages homogenously filled with ZnSe and CoSe2 nanodots as excellent anode materials for lithium- and sodium-ion batteries. J. Mater. Chem. A 7(18), 11016–11037 (2019). https://doi.org/10.1039/c9ta01999e
  134. G. Fang, Z. Wu, J. Zhou, C. Zhu, X. Cao et al., Observation of pseudocapacitive effect and fast ion diffusion in bimetallic sulfides as an advanced sodium-ion battery anode. Adv. Energy Mater. 8(19), 1703155 (2018). https://doi.org/10.1002/aenm.201703155
  135. G. Fang, Q. Wang, J. Zhou, Y. Lei, Z. Chen et al., Metal organic framework-templated synthesis of bimetallic selenides with rich phase boundaries for sodium-ion storage and oxygen evolution reaction. ACS Nano 13(5), 5635–5645 (2019). https://doi.org/10.1021/acsnano.9b00816
  136. X. Liu, Y. Liu, M. Feng, L.-Z. Fan, MOF-derived and nitrogen-doped ZnSe polyhedra encapsulated by reduced graphene oxide as the anode for lithium and sodium storage. J. Mater. Chem. A 6(46), 23621–23627 (2018). https://doi.org/10.1039/c8ta09247h
  137. W. Ren, H. Zhang, C. Guan, C. Cheng, Ultrathin MoS2 nanosheets@metal organic framework-derived N-doped carbon nanowall arrays as sodium ion battery anode with superior cycling life and rate capability. Adv. Funct. Mater. 27(32), 1702116 (2017). https://doi.org/10.1002/adfm.201702116
  138. C. Chen, M. Wu, Z. Xu, T. Feng, J. Yang et al., Tailored N-doped porous carbon nanocomposites through MOF self-assembling for Li/Na ion batteries. J Colloid Interface Sci. 538, 267–276 (2019). https://doi.org/10.1016/j.jcis.2018.11.101
  139. D. Cao, W. Kang, W. Wang, K. Sun, Y. Wang et al., Okra-like Fe7S8 /C@ZnS/N-C@C with core-double-shelled structures as robust and high-rate sodium anode. Small 16(35), 1907641 (2020). https://doi.org/10.1002/smll.201907641
  140. Y.M. Chen, X.Y. Li, K. Park, W. Lu, C. Wang et al., Nitrogen-doped carbon for sodium-ion battery anode by self-etching and graphitization of bimetallic MOF-based composite. Chem 3(1), 152–163 (2017). https://doi.org/10.1016/j.chempr.2017.05.021
  141. N. Mubarak, M. Ihsan-Ul-Haq, H. Huang, J. Cui, S. Yao et al., Metal–organic framework-induced mesoporous carbon nanofibers as an ultrastable Na metal anode host. J. Mater. Chem. A 8(20), 10269–10282 (2020). https://doi.org/10.1039/d0ta00359j
  142. S. Dong, C. Li, X. Ge, Z. Li, X. Miao et al., ZnS-Sb2S3@C core-double shell polyhedron structure derived from metal–organic framework as anodes for high performance sodium ion batteries. ACS Nano 11(6), 6474–6482 (2017). https://doi.org/10.1021/acsnano.7b03321
  143. L.T. Yu, J. Liu, X.J. Xu, L.G. Zhang, R.Z. Hu et al., Ilmenite nanotubes for high stability and high rate sodium-ion battery anodes. ACS Nano 11(5), 5120–5129 (2017). https://doi.org/10.1021/acsnano.7b02136
  144. S.H. Yang, S.-K. Park, J.K. Kim, Y.C. Kang, A mof-mediated strategy for constructing human backbone-like CoMoS3@N-doped carbon nanostructures with multiple voids as a superior anode for sodium-ion batteries. J. Mater. Chem. A 7(22), 13751–13761 (2019). https://doi.org/10.1039/C9TA03873F
  145. X. Bie, K. Kubota, T. Hosaka, K. Chihara, S. Komaba, A novel K-ion battery: hexacyanoferrate(ii)/graphite cell. J. Mater. Chem. A 5(9), 4325–4330 (2017). https://doi.org/10.1039/C7TA00220C
  146. L. Li, Z. Hu, Y. Lu, C. Wang, Q. Zhang et al., A low-strain potassium-rich prussian blue analogue cathode for high power potassium-ion batteries. Angew. Chem. Int. Ed. 60(23), 13050–13056 (2021). https://doi.org/10.1002/anie.202103475
  147. J.Y. Liao, Q. Hu, J.X. Mu, X.D. He, S. Wang et al., A vanadium-based metal-organic phosphate framework material K2[(VO)2(HPO4)2(C2O4)] as a cathode for potassium-ion batteries. Chem. Commun. 55(5), 659–662 (2019). https://doi.org/10.1039/c8cc08734b
  148. Y.L. An, H.F. Fei, Z. Zhang, L.J. Ci, S.L. Xiong et al., A titanium-based metal-organic framework as an ultralong cycle-life anode for PIBs. Chemical Commun. 53(59), 8360–8363 (2017). https://doi.org/10.1039/c7cc03606j
  149. C. Li, X.S. Hu, B.W. Hu, Cobalt(ii) dicarboxylate-based metal-organic framework for long-cycling and high-rate potassium-ion battery anode. Electrochim. Acta 253, 439–444 (2017). https://doi.org/10.1016/j.electacta.2017.09.090
  150. E. Nossol, V.H.R. Souza, A.J.G. Zarbin, Carbon nanotube/prussian blue thin films as cathodes for flexible, transparent and ITO-free potassium secondary battery. J. Colloid Interface Sci. 478, 107–116 (2016). https://doi.org/10.1016/j.jcis.2016.05.056
  151. J. Li, H. Zhao, J. Wang, N. Li, M. Wu et al., Interplanar space-controllable carboxylate pillared metal organic framework ultrathin nanosheet for superhigh capacity rechargeable alkaline battery. Nano Energy 62, 876–882 (2019). https://doi.org/10.1016/j.nanoen.2019.06.009
  152. P. Xiao, S. Li, C. Yu, Y. Wang, Y. Xu, Interface engineering between the metal-organic framework nanocrystal and graphene toward ultrahigh potassium-ion storage performance. ACS Nano 14(8), 10210–10218 (2020). https://doi.org/10.1021/acsnano.0c03488
  153. Y.P. Li, C.H. Yang, F.H. Zheng, X. Ou, Q.C. Pan et al., High pyridine N-doped porous carbon derived from metal-organic frameworks for boosting potassium-ion storage. J. Mater. Chem. A 6(37), 17959–17966 (2018). https://doi.org/10.1039/c8ta06652c
  154. J. Lu, C. Wang, H. Yu, S. Gong, G. Xia et al., Oxygen/fluorine dual-doped porous carbon nanopolyhedra enabled ultrafast and highly stable potassium storage. Adv. Funct. Mater. 29(49), 1906126 (2019). https://doi.org/10.1002/adfm.201906126
  155. G.Y. Ma, C.J. Li, F. Liu, M.K. Majeed, Z.Y. Feng et al., Metal-organic framework-derived Co0.85Se nanoparticles in N-doped carbon as a high-rate and long-lifespan anode material for potassium ion batteries. Mater. Today Energy 10, 241–248 (2018). https://doi.org/10.1016/j.mtener.2018.09.013
  156. S.L. Su, Q. Liu, J. Wang, L. Fan, R.F. Ma et al., Control of SEI formation for stable potassium-ion battery anodes by Bi-MOF-derived nanocomposites. ACS Appl. Mater. Interfaces 11(25), 22474–22480 (2019). https://doi.org/10.1021/acsami.9b06379
  157. J. Xie, X. Li, H. Lai, Z. Zhao, J. Li et al., A robust solid electrolyte interphase layer augments the ion storage capacity of bimetallic-sulfide-containing potassium-ion batteries. Angew. Chem. Int. Ed. 58(41), 14740–14747 (2019). https://doi.org/10.1002/anie.201908542
  158. C. Atangana Etogo, H. Huang, H. Hong, G. Liu, L. Zhang, Metal–organic-frameworks-engaged formation of Co0.85Se@C nanoboxes embedded in carbon nanofibers film for enhanced potassium-ion storage. Energy Storage Mater. 24, 167–176 (2020). https://doi.org/10.1016/j.ensm.2019.08.022
  159. X. Zhou, L. Chen, W. Zhang, J. Wang, Z. Liu et al., Three-dimensional ordered macroporous metal-organic framework single crystal-derived nitrogen-doped hierarchical porous carbon for high-performance potassium-ion batteries. Nano Lett. 19(8), 4965–4973 (2019). https://doi.org/10.1021/acs.nanolett.9b01127
  160. R. Trócoli, F. La Mantia, An aqueous zinc-ion battery based on copper hexacyanoferrate. Chemsuschem 8(3), 481–485 (2015). https://doi.org/10.1002/cssc.201403143
  161. M.S. Chae, J.W. Heo, H.H. Kwak, H. Lee, S.-T. Hong, Organic electrolyte-based rechargeable zinc-ion batteries using potassium nickel hexacyanoferrate as a cathode material. J. Power Sources 337, 204–211 (2017). https://doi.org/10.1016/j.jpowsour.2016.10.083
  162. X.-W. Lou, Construction of Co-Mn prussian blue analog hollow spheres for efficient aqueous Zn-ion batteries. Angew. Chem. Int. Ed. (2021). https://doi.org/10.1002/anie.202107697
  163. L. Zhang, L. Chen, X. Zhou, Z. Liu, Towards high-voltage aqueous metal-ion batteries beyond 1.5 V: the zinc/zinc hexacyanoferrate system. Adv. Energy Mater. 5(2), 1400930 (2015). https://doi.org/10.1002/aenm.201400930
  164. K.W. Nam, S.S. Park, R. dos Reis, V.P. Dravid, H. Kim et al., Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries. Nat. Commun. 10, 4948 (2019). https://doi.org/10.1038/s41467-019-12857-4
  165. H. Yang, Z. Chang, Y. Qiao, H. Deng, X. Mu et al., Constructing a super-saturated electrolyte front surface for stable rechargeable aqueous zinc batteries. Angew. Chem. Int. Ed. 59(24), 9377–9381 (2020). https://doi.org/10.1002/anie.202001844
  166. X. Pu, B. Jiang, X. Wang, W. Liu, L. Dong et al., High-performance aqueous zinc-ion batteries realized by MOF materials. Nano-Micro Lett. 12(1), 152 (2020). https://doi.org/10.1007/s40820-020-00487-1
  167. B. He, Q. Zhang, P. Man, Z. Zhou, C. Li et al., Self-sacrificed synthesis of conductive vanadium-based metal-organic framework nanowire-bundle arrays as binder-free cathodes for high-rate and high-energy-density wearable Zn-ion batteries. Nano Energy 64, 103935 (2019). https://doi.org/10.1016/j.nanoen.2019.103935
  168. Z. Wang, J. Hu, L. Han, Z. Wang, H. Wang et al., A MOF-based single-ion Zn2+ solid electrolyte leading to dendrite-free rechargeable Zn batteries. Nano Energy 56, 92–99 (2019). https://doi.org/10.1016/j.nanoen.2018.11.038
  169. C.C. Hou, Y. Wang, L. Zou, M. Wang, H. Liu et al., A gas-steamed MOF route to P-doped open carbon cages with enhanced Zn-ion energy storage capability and ultrastability. Adv. Mater. (2021). https://doi.org/10.1002/adma.202101698
  170. S. Deng, Z. Yuan, Z. Tie, C. Wang, L. Song et al., Electrochemically induced MOF-derived amorphous V2O5 for superior rate aqueous Zn-ion batteries. Angew. Chem. Int. Ed. 59(49), 22002–22006 (2020). https://doi.org/10.1002/anie.202010287
  171. Z. Wang, J.H. Huang, Z.W. Guo, X.L. Dong, Y. Liu et al., A metal-organic framework host for highly reversible dendrite-free zinc metal anodes. Joule 3(5), 1289–1300 (2019). https://doi.org/10.1016/j.joule.2019.02.012
  172. R. Yuksel, O. Buyukcakir, W.K. Seong, R.S. Ruoff, Metal-organic framework integrated anodes for aqueous zinc-ion batteries. Adv. Energy Mater. 10(16), 1904215 (2020). https://doi.org/10.1002/aenm.201904215
  173. Y. Fu, Q. Wei, G. Zhang, X. Wang, J. Zhang et al., High-performance reversible aqueous Zn-ion battery based on porous MnOx nanorods coated by MOF-derived N-doped carbon. Adv. Energy Mater. 8(26), 1801445 (2018). https://doi.org/10.1002/aenm.201801445
  174. Q. Tan, X. Li, B. Zhang, X. Chen, Y. Tian et al., Valence engineering via in situ carbon reduction on octahedron sites Mn3O4 for ultra-long cycle life aqueous Zn-ion battery. Adv. Energy Mater. 10(38), 2001050 (2020). https://doi.org/10.1002/aenm.202001050
  175. J.-H. Lee, R. Kim, S. Kim, J. Heo, H. Kwon et al., Dendrite-free Zn electrodeposition triggered by interatomic orbital hybridization of Zn and single vacancy carbon defects for aqueous zn-based flow batteries. Energy Environ. Sci. 13, 2839–2848 (2020). https://doi.org/10.1039/d0ee00723d
  176. S.S. Shinde, C.H. Lee, J.-Y. Jung, N.K. Wagh, S.-H. Kim et al., Unveiling dual-linkage 3D hexaiminobenzene metal-organic frameworks towards long-lasting advanced reversible Zn-air batteries. Energy Environ. Sci. 12(2), 727–738 (2019). https://doi.org/10.1039/c8ee02679c
  177. H. Pourfarzad, M. Shabani-Nooshabadi, M.R. Ganjali, Novel bi-functional electrocatalysts based on the electrochemical synthesized bimetallicmetal organic frameworks: Towards high energy advanced reversible zinc-air batteries. J. Power Sources 451, 227768 (2020). https://doi.org/10.1016/j.jpowsour.2020.227768
  178. G. Chen, J. Zhang, F. Wang, L. Wang, Z. Liao et al., Cobalt-based metal-organic framework nanoarrays as bifunctional oxygen electrocatalysts for rechargeable Zn-air batteries. Chem. Eur. J. 24(69), 18413–18418 (2018). https://doi.org/10.1002/chem.201804339
  179. X. Zheng, Y. Cao, D. Liu, M. Cai, J. Ding et al., Bimetallic metal-organic-framework/reduced graphene oxide composites as bifunctional electrocatalysts for rechargeable Zn-air batteries. ACS Appl. Mater. Interfaces 11(17), 15662–15669 (2019). https://doi.org/10.1021/acsami.9b02859
  180. Y. Jiang, Y.-P. Deng, R. Liang, J. Fu, R. Gao et al., d-Orbital steered active sites through ligand editing on heterometal imidazole frameworks for rechargeable zinc-air battery. Nat. Commun. 11(1), 5858 (2020). https://doi.org/10.1038/s41467-020-19709-6
  181. F. Yang, J. Xie, X. Liu, G. Wang, X. Lu, Linker defects triggering boosted oxygen reduction activity of Co/Zn-ZIF nanosheet arrays for rechargeable Zn-air batteries. Small 17(3), 2007085 (2021). https://doi.org/10.1002/smll.202007085
  182. L. Zhao, B. Dong, S. Li, L. Zhou, L. Lai et al., Interdiffusion reaction-assisted hybridization of two-dimensional metal–organic frameworks and Ti3C2Tx nanosheets for electrocatalytic oxygen evolution. ACS Nano 11(6), 5800–5807 (2017). https://doi.org/10.1021/acsnano.7b01409
  183. Z. Liang, H. Guo, G. Zhou, K. Guo, B. Wang et al., Metal–organic-framework-supported molecular electrocatalysis for the oxygen reduction reaction. Angew. Chem. Int. Ed. 60(15), 8472–8476 (2021). https://doi.org/10.1002/anie.202016024
  184. Y. Qian, Z. Hu, X. Ge, S. Yang, Y. Peng et al., A metal-free ORR/OER bifunctional electrocatalyst derived from metal-organic frameworks for rechargeable Zn-air batteries. Carbon 111, 641–650 (2017). https://doi.org/10.1016/j.carbon.2016.10.046
  185. A.I. Douka, Y. Xu, H. Yang, S. Zaman, Y. Yan et al., A zeolitic-imidazole frameworks-derived interconnected macroporous carbon matrix for efficient oxygen electrocatalysis in rechargeable zinc-air batteries. Adv. Mater. 32(28), 2002170 (2020). https://doi.org/10.1002/adma.202002170
  186. Z. Wu, H. Wu, T. Niu, S. Wang, G. Fu et al., Sulfurated metal–organic framework-derived nanocomposites for efficient bifunctional oxygen electrocatalysis and rechargeable Zn–air battery. ACS Sustain. Chem. Eng. 8(24), 9226–9234 (2020). https://doi.org/10.1021/acssuschemeng.0c03570
  187. M. Zhang, Q. Dai, H. Zheng, M. Chen, L. Dai, Novel MOF-derived Co@N-C bifunctional catalysts for highly efficient Zn-air batteries and water splitting. Adv. Mater. 30(10), 1705431 (2018). https://doi.org/10.1002/adma.201705431
  188. X.F. Lu, Y. Chen, S. Wang, S. Gao, X.W. Lou, Interfacing manganese oxide and cobalt in porous graphitic carbon polyhedrons boosts oxygen electrocatalysis for Zn–air batteries. Adv. Mater. 31(39), 1902339 (2019). https://doi.org/10.1002/adma.201902339
  189. D. Ren, J. Ying, M. Xiao, Y.P. Deng, J. Ou et al., Hierarchically porous multimetal-based carbon nanorod hybrid as an efficient oxygen catalyst for rechargeable zinc–air batteries. Adv. Funct. Mater. 30(7), 1908167 (2019). https://doi.org/10.1002/adfm.201908167
  190. Y. Xu, P. Deng, G. Chen, J. Chen, Y. Yan et al., 2D nitrogen-doped carbon nanotubes/graphene hybrid as bifunctional oxygen electrocatalyst for long-life rechargeable Zn-air batteries. Adv. Funct. Mater. 30(6), 1906081 (2020). https://doi.org/10.1002/adfm.201906081
  191. C. Guan, A. Sumboja, H. Wu, W. Ren, X. Liu et al., Hollow Co3O4 nanosphere embedded in carbon arrays for stable and flexible solid-state zinc-air batteries. Adv. Mater. 29(44), 1704117 (2017). https://doi.org/10.1002/adma.201704117
  192. Q. Zhou, Z. Zhang, J. Cai, B. Liu, Y. Zhang et al., Template-guided synthesis of Co nanoparticles embedded in hollow nitrogen doped carbon tubes as a highly efficient catalyst for rechargeable Zn-air batteries. Nano Energy 71, 104592 (2020). https://doi.org/10.1016/j.nanoen.2020.104592
  193. D. Ji, L. Fan, L. Li, S. Peng, D. Yu et al., Atomically transition metals on self-supported porous carbon flake arrays as binder-free air cathode for wearable zinc-air batteries. Adv. Mater. 31(16), 1808267 (2019). https://doi.org/10.1002/adma.201808267
  194. Y. Arafat, M.R. Azhar, Y. Zhong, X. Xu, M.O. Tadé et al., A porous nano-micro-composite as a high-performance bi-functional air electrode with remarkable stability for rechargeable zinc–air batteries. Nano-Micro Lett. 12, 130 (2020). https://doi.org/10.1007/s40820-020-00468-4
  195. D. Chen, X. Chen, Z. Cui, G. Li, B. Han et al., Dual-active-site hierarchical architecture containing NiFe-LDH and ZIF-derived carbon-based framework composite as efficient bifunctional oxygen electrocatalysts for durable rechargeable Zn-air batteries. Chem. Eng. J. 399, 125718 (2020). https://doi.org/10.1016/j.cej.2020.125718
  196. Y.-N. Chen, Y. Guo, H. Cui, Z. Xie, X. Zhang et al., Bifunctional electrocatalysts of MOF-derived Co-N/C on bamboo-like MnO nanowires for high-performance liquid- and solid-state Zn-air batteries. J. Mater. Chem. A 6(20), 9716–9722 (2018). https://doi.org/10.1039/c8ta01859f
  197. X. Gao, Y. Du, J. Zhou, S. Li, P. Qi et al., Large-scale production of MOF-derived coatings for functional interlayers in high-performance Li–S batteries. ACS Appl. Energy Mater. 1(12), 6986–6991 (2018). https://doi.org/10.1021/acsaem.8b01401
  198. G.K. Gao, Y.R. Wang, H.J. Zhu, Y. Chen, R.X. Yang et al., Rapid production of metal–organic frameworks based separators in industrial-level efficiency. Adv. Sci. 7(24), 2002190 (2020). https://doi.org/10.1002/advs.202002190
Read More
Author biographies are not available.
Download this PDF file
PDF
Statistic
Read Counter : 5607 Download : 4233

Most read articles by the same author(s)