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Vol. 13 (2021)

Ternary MOF-Based Redox Active Sites Enabled 3D-on-2D Nanoarchitectured Battery-Type Electrodes for High-Energy-Density Supercapatteries

https://doi.org/10.1007/s40820-020-00528-9
Goli Nagaraju
Institute for Wearable Convergence Electronics, Department of Electronic Engineering, Kyung Hee University, 1732 Deogyeong‑daero, Gihung‑gu, Yongin‑si, Gyeonggi‑do 17104, Republic of Korea
S. Chandra Sekhar
Institute for Wearable Convergence Electronics, Department of Electronic Engineering, Kyung Hee University, 1732 Deogyeong‑daero, Gihung‑gu, Yongin‑si, Gyeonggi‑do 17104, Republic of Korea
Bhimanaboina Ramulu
Institute for Wearable Convergence Electronics, Department of Electronic Engineering, Kyung Hee University, 1732 Deogyeong‑daero, Gihung‑gu, Yongin‑si, Gyeonggi‑do 17104, Republic of Korea
Sk. Khaja Hussain
Institute for Wearable Convergence Electronics, Department of Electronic Engineering, Kyung Hee University, 1732 Deogyeong‑daero, Gihung‑gu, Yongin‑si, Gyeonggi‑do 17104, Republic of Korea
D. Narsimulu
Institute for Wearable Convergence Electronics, Department of Electronic Engineering, Kyung Hee University, 1732 Deogyeong‑daero, Gihung‑gu, Yongin‑si, Gyeonggi‑do 17104, Republic of Korea
Jae Su Yu
Institute for Wearable Convergence Electronics, Department of Electronic Engineering, Kyung Hee University, 1732 Deogyeong‑daero, Gihung‑gu, Yongin‑si, Gyeonggi‑do 17104, Republic of Korea

Corresponding Author: Jae Su Yu

jsyu@khu.ac.kr

Nano-Micro Letters, Vol. 13 (2021), Article Number: 17

Abstract

Designing rationally combined metal–organic frameworks (MOFs) with multifunctional nanogeometries is of significant research interest to enable the electrochemical properties in advanced energy storage devices. Herein, we explored a new class of binder-free dual-layered Ni–Co–Mn-based MOFs (NCM-based MOFs) with three-dimensional (3D)-on-2D nanoarchitectures through a polarity-induced solution-phase method for high-performance supercapatteries. The hierarchical NCM-based MOFs having grown on nickel foam exhibit a battery-type charge storage mechanism with superior areal capacity (1311.4 μAh cm−2 at 5 mA cm−2), good rate capability (61.8%; 811.67 μAh cm−2 at 50 mA cm−2), and an excellent cycling durability. The superior charge storage properties are ascribed to the synergistic features, higher accessible active sites of dual-layered nanogeometries, and exalted redox chemistry of multi metallic guest species, respectively. The bilayered NCM-based MOFs are further employed as a battery-type electrode for the fabrication of supercapattery paradigm with biomass-derived nitrogen/oxygen doped porous carbon as a negative electrode, which demonstrates excellent capacity of 1.6 mAh cm−2 along with high energy and power densities of 1.21 mWh cm−2 and 32.49 mW cm−2, respectively. Following, the MOF-based supercapattery was further assembled with a renewable solar power harvester to use as a self-charging station for various portable electronic applications.


Highlights:


1 Redox chemistry enabled Ni–Co–Mn (NCM)-based MOF nanoarchitectures are used as battery-type electrodes.
2 The NCM-based MOFs demonstrate high areal capacity and good cycling stability.
3 The fabricated hybrid supercapattery showed high energy and power densities of 1.21 mWh cm−2 and 32.49 mW cm−2, respectively.

Keywords

Metal–organic frameworks Dual layers Redox chemistry Supercapattery Renewable energy
Nagaraju, Goli, S. Chandra Sekhar, Bhimanaboina Ramulu, Sk. Khaja Hussain, D. Narsimulu, and Jae Su Yu. 2020. “Ternary MOF-Based Redox Active Sites Enabled 3D-on-2D Nanoarchitectured Battery-Type Electrodes for High-Energy-Density Supercapatteries”. Nano-Micro Letters 13 (November):17. https://doi.org/10.1007/s40820-020-00528-9.
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References
  1. G. Nagaraju, S.C. Sekhar, B. Ramulu, L.K. Bharat, G.S.R. Raju, Y.-K. Han, J.S. Yu, Enabling redox chemistry with hierarchically designed bilayered nanoarchitectures for pouch-type hybrid supercapacitors: a sunlight-driven rechargeable energy storage system to portable electronics. Nano Energy 50, 448–461 (2018). https://doi.org/10.1016/j.nanoen.2018.05.063
  2. X. Liu, K. Zhao, Z.L. Wang, Y. Yang, Unity convoluted design of solid Li-ion battery and triboelectric nanogenerator for self-powered wearable electronics. Adv. Energy Mater. 7(22), 1701629 (2017). https://doi.org/10.1002/aenm.201701629
  3. K. Zhao, Y. Yang, X. Liu, Z.L. Wang, Triboelectrification-enabled self-charging lithium-ion batteries. Adv. Energy Mater. 7(21), 1700103 (2017). https://doi.org/10.1002/aenm.201700103
  4. C. Liu, S. Wang, C. Zhang, H. Fu, X. Nan, Y. Yang, G. Cao, High power high safety battery with electrospun Li3V2(PO4)3 cathode and Li4Ti5O12 anode with 95% energy efficiency. Energy Storag. Mater. 5, 93–102 (2016). https://doi.org/10.1016/j.ensm.2016.06.004
  5. C. Han, H. Li, R. Shi, L. Xu, J. Li, F. Kang, B. Li, Nanostructured anode materials for non-aqueous lithium ion hybrid capacitors. Energy Environ. Mater. 1(2), 75–87 (2018). https://doi.org/10.1002/eem2.12009
  6. S. Zhu, Z. Wang, F. Huang, H. Zhang, S. Li, Hierarchical Cu(OH)2@Ni2(OH)2CO3 core/shell nanowire arrays in situ grown on three-dimensional copper foam for high-performance solid-state supercapacitors. J. Mater. Chem. A 5(20), 9960–9969 (2017). https://doi.org/10.1039/C7TA01805C
  7. G. Nagaraju, Y.H. Ko, J.S. Yu, Tricobalt tetroxide nanoplate arrays on flexible conductive fabric substrate: facile synthesis and application for electrochemical supercapacitors. J. Power Sources 283, 251–259 (2015). https://doi.org/10.1016/j.jpowsour.2015.02.104
  8. X. Li, Q. Liu, S. Chen, W. Li, Z. Liang et al., Quasi-aligned SiC@C nanowire arrays as free-standing electrodes for high-performance micro-supercapacitors. Energy Storage Mater. 27, 261–269 (2020). https://doi.org/10.1016/j.ensm.2020.02.009
  9. Y. Zhu, Z. Wu, M. Jing, X. Yang, W. Song, X. Ji, Mesoporous NiCo2S4 nanoparticles as high-performance electrode materials for supercapacitors. J. Power Sources 273, 584–590 (2015). https://doi.org/10.1016/j.jpowsour.2014.09.144
  10. N. Goli, S.S. Chandra, Y.J. Su, Utilizing waste cable wires for high-performance fiber-based hybrid supercapacitors: an effective approach to electronic-waste management. Adv. Energy Mater. 8(7), 1702201 (2018). https://doi.org/10.1002/aenm.201702201
  11. Y. Jiang, J. Liu, Definitions of pseudocapacitive materials: a brief review. Energy Environ. Mater. 2(1), 30–37 (2019). https://doi.org/10.1002/eem2.12028
  12. G. Nagaraju, S.C. Sekhar, G.S. Rama Raju, L.K. Bharat, J.S. Yu, Designed construction of yolk-shell structured trimanganese tetraoxide nanospheres via polar solvent-assisted etching and biomass-derived activated porous carbon materials for high-performance asymmetric supercapacitors. J. Mater. Chem. A 5(30), 15808–15821 (2017). https://doi.org/10.1039/C7TA04314G
  13. G.K. Veerasubramani, K. Krishnamoorthy, S.J. Kim, Improved electrochemical performances of binder-free CoMoO4 nanoplate arrays@Ni foam electrode using redox additive electrolyte. J. Power Sources 306, 378–386 (2016). https://doi.org/10.1016/j.jpowsour.2015.12.034
  14. N. Goli, C.S. Min, S.S. Chandra, Y.J. Su, Metallic layered polyester fabric enabled nickel selenide nanostructures as highly conductive and binderless electrode with superior energy storage performance. Adv. Energy Mater. 7(4), 1601362 (2017). https://doi.org/10.1002/aenm.201601362
  15. X.-Y. Yu, L. Yu, X.W. Lou, Metal sulfide hollow nanostructures for electrochemical energy storage. Adv. Energy Mater. 6(3), 1501333 (2016). https://doi.org/10.1002/aenm.201501333
  16. B.C. Kim, R. Manikandan, K.H. Yu, M.-S. Park, D.-W. Kim, S.Y. Park, C. Justin Raj, Efficient supercapattery behavior of mesoporous hydrous and anhydrous cobalt molybdate nanostructures. J. Alloys Compd. 789, 256–265 (2019). https://doi.org/10.1016/j.jallcom.2019.03.033
  17. W. Zuo, R. Li, C. Zhou, Y. Li, J. Xia, J. Liu, Battery-supercapacitor hybrid devices: recent progress and future prospects. Adv. Sci. 4(7), 1600539 (2017). https://doi.org/10.1002/advs.201600539
  18. H. Shao, N. Padmanathan, D. McNulty, C. O’Dwyer, K.M. Razeeb, Cobalt phosphate-based supercapattery as alternative power source for implantable medical devices. ACS Appl. Energy Mater. 2(1), 569–578 (2019). https://doi.org/10.1021/acsaem.8b01612
  19. K.V. Sankar, S.C. Lee, Y. Seo, C. Ray, S. Liu, A. Kundu, S.C. Jun, Binder-free cobalt phosphate one-dimensional nanograsses as ultrahigh-performance cathode material for hybrid supercapacitor applications. J. Power Sources 373, 211–219 (2018). https://doi.org/10.1016/j.jpowsour.2017.11.013
  20. Z. Yu, L. Tetard, L. Zhai, J. Thomas, Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions. Energy Environ. Sci. 8(3), 702–730 (2015). https://doi.org/10.1039/C4EE03229B
  21. W. Zuo, C. Xie, P. Xu, Y. Li, J. Liu, A novel phase-transformation activation process toward Ni–Mn–O nanoprism arrays for 2.4v ultrahigh-voltage aqueous supercapacitors. Adv. Mater. 29(36), 1703463 (2017). https://doi.org/10.1002/adma.201703463
  22. D.T. Lee, J.D. Jamir, G.W. Peterson, G.N. Parsons, Water-stable chemical-protective textiles via euhedral surface-oriented 2d Cu–TCPP metal-organic frameworks. Small 15(10), 1805133 (2019). https://doi.org/10.1002/smll.201805133
  23. H. Furukawa, N. Ko, Y.B. Go, N. Aratani, S.B. Choi et al., Ultrahigh porosity in metal-organic frameworks. Science 329(5990), 424–428 (2010). https://doi.org/10.1126/science.1192160
  24. L. Zou, C.-C. Hou, Z. Liu, H. Pang, Q. Xu, Superlong single-crystal metal–organic framework nanotubes. JACS 140(45), 15393–15401 (2018). https://doi.org/10.1021/jacs.8b09092
  25. C. Qu, Y. Jiao, B. Zhao, D. Chen, R. Zou, K.S. Walton, M. Liu, Nickel-based pillared MOFs for high-performance supercapacitors: design, synthesis and stability study. Nano Energy 26, 66–73 (2016). https://doi.org/10.1016/j.nanoen.2016.04.003
  26. G. Zhu, H. Wen, M. Ma, W. Wang, L. Yang et al., A self-supported hierarchical Co-MOF as a supercapacitor electrode with ultrahigh areal capacitance and excellent rate performance. Chem. Commun. 54(74), 10499–10502 (2018). https://doi.org/10.1039/C8CC03669A
  27. H. Shiozawa, B.C. Bayer, H. Peterlik, J.C. Meyer, W. Lang, T. Pichler, Doping of metal–organic frameworks towards resistive sensing. Sci. Rep. 7(1), 2439 (2017). https://doi.org/10.1038/s41598-017-02618-y
  28. J. Yang, C. Zheng, P. Xiong, Y. Li, M. Wei, Zn-doped Ni-MOF material with a high supercapacitive performance. J. Mater. Chem. A 2(44), 19005–19010 (2014). https://doi.org/10.1039/C4TA04346D
  29. Y. Jiao, J. Pei, D. Chen, C. Yan, Y. Hu, Q. Zhang, G. Chen, Mixed-metallic mof based electrode materials for high performance hybrid supercapacitors. J. Mater. Chem. A 5(3), 1094–1102 (2017). https://doi.org/10.1039/C6TA09805C
  30. Q. Qian, Y. Li, Y. Liu, L. Yu, G. Zhang, Ambient fast synthesis and active sites deciphering of hierarchical foam-like trimetal–organic framework nanostructures as a platform for highly efficient oxygen evolution electrocatalysis. Adv. Mater. 1, 1901139 (2019). https://doi.org/10.1002/adma.201901139
  31. X. Zheng, Y. Cao, D. Liu, M. Cai, J. Ding et al., Bimetallic metal–organic-framework/reduced graphene oxide composites as bifunctional electrocatalysts for rechargeable Zn–air batteries. ACS Appl. Mater. Interfaces. 11(17), 15662–15669 (2019). https://doi.org/10.1021/acsami.9b02859
  32. Y. Wang, Y. Liu, H. Wang, W. Liu, Y. Li, J. Zhang, H. Hou, J. Yang, Ultrathin NiCo-MOF nanosheets for high-performance supercapacitor electrodes. ACS Appl. Energy Mater. 2(3), 2063–2071 (2019). https://doi.org/10.1021/acsaem.8b02128
  33. S.H. Kazemi, B. Hosseinzadeh, H. Kazemi, M.A. Kiani, S. Hajati, Facile synthesis of mixed metal–organic frameworks: electrode materials for supercapacitors with excellent areal capacitance and operational stability. ACS Appl. Mater. Interfaces. 10(27), 23063–23073 (2018). https://doi.org/10.1021/acsami.8b04502
  34. Q. Qian, Y. Li, Y. Liu, L. Yu, G. Zhang, Ambient fast synthesis and active sites deciphering of hierarchical foam-like trimetal–organic framework nanostructures as a platform for highly efficient oxygen evolution electrocatalysis. Adv. Mater. 31(23), 1901139 (2019). https://doi.org/10.1002/adma.201901139
  35. Y. Chi, W. Yang, Y. Xing, Y. Li, H. Pang, Q. Xu, Ni/Co bimetallic organic framework nanosheet assemblies for high-performance electrochemical energy storage. Nanoscale 12(19), 10685–10692 (2020). https://doi.org/10.1039/D0NR02016H
  36. M. Zhou, F. Xu, S. Zhang, B. Liu, Y. Yang, K. Chen, J. Qi, Low consumption design of hollow NiCo-lDH nanoflakes derived from mofs for high-capacity electrode materials. J. Mater. Sci.-Mater. Electron. 31(4), 3281–3288 (2020). https://doi.org/10.1007/s10854-020-02876-z
  37. M. Guo, K. Li, L. Liu, H. Zhang, W. Guo et al., Manganese-based multi-oxide derived from spent ternary lithium-ions batteries as high-efficient catalyst for VOCs oxidation. J. Hazardous Mater. 380, 120905 (2019). https://doi.org/10.1016/j.jhazmat.2019.120905
  38. L.G. Beka, X. Bu, X. Li, X. Wang, C. Han, W. Liu, A 2d metal–organic framework/reduced graphene oxide heterostructure for supercapacitor application. RSC Adv. 9(62), 36123–36135 (2019). https://doi.org/10.1039/C9RA07061C
  39. G. Nagaraju, G.S.R. Raju, Y.H. Ko, J.S. Yu, Hierarchical Ni-Co layered double hydroxide nanosheets entrapped on conductive textile fibers: a cost-effective and flexible electrode for high-performance pseudocapacitors. Nanoscale 8(2), 812–825 (2016). https://doi.org/10.1039/C5NR05643H
  40. I. Shakir, M. Shahid, H.W. Yang, D.J. Kang, Structural and electrochemical characterization of α-moo3 nanorod-based electrochemical energy storage devices. Electrochim. Acta 56(1), 376–380 (2010). https://doi.org/10.1016/j.electacta.2010.09.028
  41. Y. Gogotsi, R.M. Penner, Energy storage in nanomaterials—capacitive, pseudocapacitive, or battery-like? ACS Nano 12(3), 2081–2083 (2018). https://doi.org/10.1021/acsnano.8b01914
  42. D. Chao, P. Liang, Z. Chen, L. Bai, H. Shen et al., Pseudocapacitive Na-ion storage boosts high rate and areal capacity of self-branched 2D layered metal chalcogenide nanoarrays. ACS Nano 10(11), 10211–10219 (2016). https://doi.org/10.1021/acsnano.6b05566
  43. V. Augustyn, J. Come, M.A. Lowe, J.W. Kim, P.-L. Taberna et al., High-rate electrochemical energy storage through Li + intercalation pseudocapacitance. Nat. Mater. 12, 518 (2013). https://doi.org/10.1038/nmat3601
  44. M. Zhang, H. Fan, X. Ren, N. Zhao, H. Peng et al., Study of pseudocapacitive contribution to superior energy storage of 3d heterostructure CoWO4/Co3O4 nanocone arrays. J. Power Sources 418, 202–210 (2019). https://doi.org/10.1016/j.jpowsour.2019.02.041
  45. G.K. Veerasubramani, M.S.P. Sudhakaran, N.R. Alluri, K. Krishnamoorthy, Y.S. Mok, S.J. Kim, Effective use of an idle carbon-deposited catalyst for energy storage applications. J. Mater. Chem. A 4(32), 12571–12582 (2016). https://doi.org/10.1039/C6TA05082D
  46. G. Nagaraju, S. Chandra Sekhar, L. Krishna Bharat, J.S. Yu, Wearable fabrics with self-branched bimetallic layered double hydroxide coaxial nanostructures for hybrid supercapacitors. ACS Nano 11(11), 10860–10874 (2017). https://doi.org/10.1021/acsnano.7b04368
  47. C.J. Raj, M. Rajesh, R. Manikandan, K.H. Yu, J.R. Anusha et al., High electrochemical capacitor performance of oxygen and nitrogen enriched activated carbon derived from the pyrolysis and activation of squid gladius chitin. J. Power Sources 386, 66–76 (2018). https://doi.org/10.1016/j.jpowsour.2018.03.038
  48. R.R. Salunkhe, J. Tang, Y. Kamachi, T. Nakato, J.H. Kim, Y. Yamauchi, Asymmetric supercapacitors using 3d nanoporous carbon and cobalt oxide electrodes synthesized from a single metal–organic framework. ACS Nano 9(6), 6288–6296 (2015). https://doi.org/10.1021/acsnano.5b01790
  49. G.K. Veerasubramani, A. Chandrasekhar, M.S.P. Sudhakaran, S. Mok, S.J. Kim, Liquid electrolyte mediated flexible pouch-type hybrid supercapacitor based on binderless core-shell nanostructures assembled with honeycomb-like porous carbon. J. Mater. Chem. A 5, 11100–11113 (2017). https://doi.org/10.1039/C7TA01308F
  50. K. Tao, X. Han, Q. Ma, L. Han, A metal–organic framework derived hierarchical nickel–cobalt sulfide nanosheet array on ni foam with enhanced electrochemical performance for supercapacitors. Dalton Trans. 47(10), 3496–3502 (2018). https://doi.org/10.1039/C7DT04942K
  51. X. Wang, B. Shi, Y. Fang, F. Rong, F. Huang, R. Que, M. Shao, High capacitance and rate capability of a Ni3S2@CdS core-shell nanostructure supercapacitor. J. Mater. Chem. A 5(15), 7165–7172 (2017). https://doi.org/10.1039/C7TA00593H
  52. Y. Yan, P. Gu, S. Zheng, M. Zheng, H. Pang, H. Xue, Facile synthesis of an accordion-like Ni-MOF superstructure for high-performance flexible supercapacitors. J. Mater. Chem. A 4(48), 19078–19085 (2016). https://doi.org/10.1039/C6TA08331E
  53. G. Nagaraju, S.C. Sekhar, B. Ramulu, G.K. Veerasubramani, D. Narsimulu, S.K. Hussain, J.S. Yu, An agriculture-inspired nanostrategy towards flexible and highly efficient hybrid supercapacitors using ubiquitous substrates. Nano Energy 66, 104054 (2019). https://doi.org/10.1016/j.nanoen.2019.104054
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