Issue

Vol. 13 (2021)

Atomic-Scale Layer-by-Layer Deposition of FeSiAl@ZnO@Al2O3 Hybrid with Threshold Anti-Corrosion and Ultra-High Microwave Absorption Properties in Low-Frequency Bands

https://doi.org/10.1007/s40820-021-00678-4
Wei Tian
National Engineering Researching Centre of Electromagnetic Radiation Control Materials, Key Laboratory of Multi‑Spectral Absorbing Materials and Structures of Ministry of Education, State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 611731, People’s Republic of China
Jinyao Li
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, People’s Republic of China
Yifan Liu
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, People’s Republic of China
Rashad Ali
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, People’s Republic of China
Yang Guo
School of Electrical and Information Engineering, Panzhihua University, Panzhihua 617000, People’s Republic of China
Longjiang Deng
National Engineering Researching Centre of Electromagnetic Radiation Control Materials, Key Laboratory of Multi‑Spectral Absorbing Materials and Structures of Ministry of Education, State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 611731, People’s Republic of China
Nasir Mahmood
School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia
Xian Jian
National Engineering Researching Centre of Electromagnetic Radiation Control Materials, Key Laboratory of Multi‑Spectral Absorbing Materials and Structures of Ministry of Education, State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 611731, People’s Republic of China

Corresponding Author: Xian Jian

jianxian@uestc.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 161

Abstract

Developing highly efficient magnetic microwave absorbers (MAs) is crucial, and yet challenging for anti-corrosion properties in extremely humid and salt-induced foggy environments. Herein, a dual-oxide shell of ZnO/Al2O3 as a robust barrier to FeSiAl core is introduced to mitigate corrosion resistance. The FeSiAl@ZnO@Al2O3 layer by layer hybrid structure is realized with atomic-scale precision through the atomic layer deposition technique. Owing to the unique hybrid structure, the FeSiAl@ZnO@Al2O3 exhibits record-high microwave absorbing performance in low-frequency bands covering L and S bands with a minimum reflection loss (RLmin) of -50.6 dB at 3.4 GHz. Compared with pure FeSiAl (RLmin of -13.5 dB, a bandwidth of 0.5 GHz), the RLmin value and effective bandwidth of this designed novel absorber increased up to ~ 3.7 and ~ 3 times, respectively. Furthermore, the inert ceramic dual-shells have improved 9.0 times the anti-corrosion property of FeSiAl core by multistage barriers towards corrosive medium and obstruction of the electric circuit. This is attributed to the large charge transfer resistance, increased impedance modulus |Z|0.01 Hz, and frequency time constant of FeSiAl@ZnO@Al2O3. The research demonstrates a promising platform toward the design of next-generation MAs with improved anti-corrosion properties.


Highlights:


1 A multiscale structure is realized through layer-by-layer deposition with atom-scale precision via atomic layer deposition
2 FeSiAl@ZnO@Al2O3 exhibits record-high absorption properties in low-frequency bands.
3 The corrosion resistance is improved by the unique multistage oxide barriers.

Keywords

Atomic layer deposition Magnetic alloy Dual-oxide-shells Microwave absorption Anti-corrosion
Tian, Wei, Jinyao Li, Yifan Liu, Rashad Ali, Yang Guo, Longjiang Deng, Nasir Mahmood, and Xian Jian. 2021. “Atomic-Scale Layer-by-Layer Deposition of FeSiAl@ZnO@Al2O3 Hybrid With Threshold Anti-Corrosion and Ultra-High Microwave Absorption Properties in Low-Frequency Bands”. Nano-Micro Letters 13 (July):161. https://doi.org/10.1007/s40820-021-00678-4.
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