Issue

Vol. 16 (2024)

Advanced Materials for NH3 Capture: Interaction Sites and Transport Pathways

https://doi.org/10.1007/s40820-024-01425-1
Hai‑Yan Jiang
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Zao‑Ming Wang
Institute for Integrated Cell‑Material Sciences (iCeMS), Kyoto University, Sakyo‑Ku, YoshidaKyoto 606‑8501, Japan
Xue‑Qi Sun
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Shao‑Juan Zeng
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Yang‑Yang Guo
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Lu Bai
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Ming‑Shui Yao
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Xiang‑Ping Zhang
Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China

Corresponding Author: Xiang‑Ping Zhang

xpzhang@ipe.ac.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 228

Abstract

Ammonia (NH3) is a carbon-free, hydrogen-rich chemical related to global food safety, clean energy, and environmental protection. As an essential technology for meeting the requirements raised by such issues, NH3 capture has been intensively explored by researchers in both fundamental and applied fields. The four typical methods used are (1) solvent absorption by ionic liquids and their derivatives, (2) adsorption by porous solids, (3) ab-adsorption by porous liquids, and (4) membrane separation. Rooted in the development of advanced materials for NH3 capture, we conducted a coherent review of the design of different materials, mainly in the past 5 years, their interactions with NH3 molecules and construction of transport pathways, as well as the structure–property relationship, with specific examples discussed. Finally, the challenges in current research and future worthwhile directions for NH3 capture materials are proposed.


Highlights:
1 An overview of advanced materials for NH3 capture from the aspects of interaction sites and transport pathways is presented.
2 The classifications, working principles, design ideas and structure–property relationships on materials for NH3 capture are discussed in detail.
3 The challenges and encouraging outlooks with worthwhile directions for NH3 capture are proposed.

Keywords

Ammonia capture Solvents Porous solids Porous liquids Membranes
Jiang, Hai‑Yan, Zao‑Ming Wang, Xue‑Qi Sun, Shao‑Juan Zeng, Yang‑Yang Guo, Lu Bai, Ming‑Shui Yao, and Xiang‑Ping Zhang. 2024. “Advanced Materials for NH3 Capture: Interaction Sites and Transport Pathways”. Nano-Micro Letters 16 (June):228. https://doi.org/10.1007/s40820-024-01425-1.
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References
  1. D. Feng, L. Zhou, T.J. White, A.K. Cheetham, T. Ma et al., Nanoengineering metal–organic frameworks and derivatives for electrosynthesis of ammonia. Nano-Micro Lett. 15, 203 (2023). https://doi.org/10.1007/s40820-023-01169-4
  2. S. Zhang, Y. Zha, Y. Ye, K. Li, Y. Lin et al., Oxygen-coordinated single Mn sites for efficient electrocatalytic nitrate reduction to ammonia. Nano-Micro Lett. 16, 9 (2023). https://doi.org/10.1007/s40820-023-01217-z
  3. Q. Hu, S. Qi, Q. Huo, Y. Zhao, J. Sun et al., Designing efficient nitrate reduction electrocatalysts by identifying and optimizing active sites of co-based spinels. J. Am. Chem. Soc. 146, 2967–2976 (2024). https://doi.org/10.1021/jacs.3c06904
  4. F.B. Juangsa, A.R. Irhamna, M. Aziz, Production of ammonia as potential hydrogen carrier: review on thermochemical and electrochemical processes. Int. J. Hydrog. Energy 46, 14455–14477 (2021). https://doi.org/10.1016/j.ijhydene.2021.01.214
  5. J. Li, S. Lai, D. Chen, R. Wu, N. Kobayashi et al., A review on combustion characteristics of ammonia as a carbon-free fuel. Front. Energy Res. 9, 760356 (2021). https://doi.org/10.3389/fenrg.2021.760356
  6. X. Li, C. Deng, Y. Kong, Q. Huo, L. Mi et al., Unlocking the transition of electrochemical water oxidation mechanism induced by heteroatom doping. Angew. Chem. Int. Ed. 62, 2309732 (2023). https://doi.org/10.1002/anie.202309732
  7. X. Li, H. Zhang, Q. Hu, W. Zhou, J. Shao et al., Amorphous NiFe oxide-based nanoreactors for efficient electrocatalytic water oxidation. Angew. Chem. Int. Ed. 62, 2300478 (2023). https://doi.org/10.1002/anie.202300478
  8. Q. Hu, K. Gao, X. Wang, H. Zheng, J. Cao et al., Subnanometric Ru clusters with upshifted D band center improve performance for alkaline hydrogen evolution reaction. Nat. Commun. 13, 3958 (2022). https://doi.org/10.1038/s41467-022-31660-2
  9. A.G. Bannov, M.V. Popov, A.E. Brester, P.B. Kurmashov, Recent advances in ammonia gas sensors based on carbon nanomaterials. Micromachines 12, 186 (2021). https://doi.org/10.3390/mi12020186
  10. R.B. Bist, S. Subedi, L. Chai, X. Yang, Ammonia emissions, impacts, and mitigation strategies for poultry production: a critical review. J. Environ. Manag. 328, 116919 (2023). https://doi.org/10.1016/j.jenvman.2022.116919
  11. K.E. Wyer, D.B. Kelleghan, V. Blanes-Vidal, G. Schauberger, T.P. Curran, Ammonia emissions from agriculture and their contribution to fine particulate matter: a review of implications for human health. J. Environ. Manag. 323, 116285 (2022). https://doi.org/10.1016/j.jenvman.2022.116285
  12. S.L. Nordahl, C.V. Preble, T.W. Kirchstetter, C.D. Scown, Greenhouse gas and air pollutant emissions from composting. Environ. Sci. Technol. 57, 2235–2247 (2023). https://doi.org/10.1021/acs.est.2c05846
  13. J. Tian, B. Liu, Ammonia capture with ionic liquid systems: a review. Crit. Rev. Environ. Sci. Technol. 52, 767–809 (2022). https://doi.org/10.1080/10643389.2020.1835437
  14. L. Zhang, H. Dong, S. Zeng, Z. Hu, S. Hussain et al., An overview of ammonia separation by ionic liquids. Ind. Eng. Chem. Res. 60, 6908–6924 (2021). https://doi.org/10.1021/acs.iecr.1c00780
  15. S. Zeng, Y. Cao, P. Li, X. Liu, X. Zhang, Ionic liquid–based green processes for ammonia separation and recovery. Curr. Opin. Green Sustain. Chem. 25, 100354 (2020). https://doi.org/10.1016/j.cogsc.2020.100354
  16. K. Vikrant, V. Kumar, K.-H. Kim, D. Kukkar, Metal–organic frameworks (MOFs): potential and challenges for capture and abatement of ammonia. J. Mater. Chem. A 5, 22877–22896 (2017). https://doi.org/10.1039/C7TA07847A
  17. T. Islamoglu, Z. Chen, M.C. Wasson, C.T. Buru, K.O. Kirlikovali et al., Metal–organic frameworks against toxic chemicals. Chem. Rev. 120, 8130–8160 (2020). https://doi.org/10.1021/acs.chemrev.9b00828
  18. Y. Zhang, X. Cui, H. Xing, Recent advances in the capture and abatement of toxic gases and vapors by metal–organic frameworks. Mater. Chem. Front. 5, 5970–6013 (2021). https://doi.org/10.1039/d1qm00516b
  19. X. Han, S. Yang, M. Schröder, Metal–organic framework materials for production and distribution of ammonia. J. Am. Chem. Soc. 145, 1998–2012 (2023). https://doi.org/10.1021/jacs.2c06216
  20. X. Sun, G. Li, S. Zeng, L. Yuan, L. Bai et al., Ultra-high NH3 absorption by triazole cation-functionalized ionic liquids through multiple hydrogen bonding. Sep. Purif. Technol. 307, 122825 (2023). https://doi.org/10.1016/j.seppur.2022.122825
  21. L. Yuan, X. Zhang, B. Ren, Y. Yang, Y. Bai et al., Dual-functionalized protic ionic liquids for efficient absorption of NH3 through synergistically physicochemical interaction. J. Chem. Technol. Biotechnol. 95, 1815–1824 (2020). https://doi.org/10.1002/jctb.6381
  22. A.J. Rieth, Y. Tulchinsky, M. Dincă, High and reversible ammonia uptake in mesoporous azolate metal–organic frameworks with open Mn Co, and Ni sites. J. Am. Chem. Soc. 138, 9401–9404 (2016). https://doi.org/10.1021/jacs.6b05723
  23. Y. Su, K.-I. Otake, J.-J. Zheng, S. Horike, S. Kitagawa et al., Separating water isotopologues using diffusion-regulatory porous materials. Nature 611, 289–294 (2022). https://doi.org/10.1038/s41586-022-05310-y
  24. A. Bavykina, A. Cadiau, J. Gascon, Porous liquids based on porous cages, metal organic frameworks and metal organic polyhedra. Coord. Chem. Rev. 386, 85–95 (2019). https://doi.org/10.1016/j.ccr.2019.01.015
  25. Z. Zhang, B. Yang, B. Zhang, M. Cui, J. Tang et al., Type II porous ionic liquid based on metal–organic cages that enables L-tryptophan identification. Nat. Commun. 13, 2353 (2022). https://doi.org/10.1038/s41467-022-30092-2
  26. H. Liu, B. Liu, L.-C. Lin, G. Chen, Y. Wu et al., A hybrid absorption-adsorption method to efficiently capture carbon. Nat. Commun. 5, 5147 (2014). https://doi.org/10.1038/ncomms6147
  27. M. Costa Gomes, L. Pison, C. Červinka, A. Padua, Porous ionic liquids or liquid metal–organic frameworks? Angew. Chem. Int. Ed. 57, 11909–11912 (2018). https://doi.org/10.1002/anie.201805495
  28. Z. Wang, A. Ozcan, G.A. Craig, F. Haase, T. Aoyama et al., Pore-networked gels: permanently porous ionic liquid gels with linked metal–organic polyhedra networks. J. Am. Chem. Soc. 145, 14456–14465 (2023). https://doi.org/10.1021/jacs.3c03778
  29. H. Dong, X. Yuan, Y. Wang, Y. Lu, H. He, Preparation of two-dimensional nanoconfined ionic liquid membrane and its molecular mechanism of CO2 separation. Chem. Eng. Sci. 283, 119393 (2024). https://doi.org/10.1016/j.ces.2023.119393
  30. B. Yang, H. Jiang, L. Bai, Y. Bai, T. Song et al., Application of ionic liquids in the mixed matrix membranes for CO2 separation: an overview. Int. J. Greenh. Gas Contr. 121, 103796 (2022). https://doi.org/10.1016/j.ijggc.2022.103796
  31. X. Zhang, X. Zhang, H. Dong, Z. Zhao, S. Zhang et al., Carbon capture with ionic liquids: overview and progress. Energy Environ. Sci. 5, 6668 (2012). https://doi.org/10.1039/c2ee21152a
  32. A. Yokozeki, M.B. Shiflett, Vapor–liquid equilibria of ammonia+ionic liquid mixtures. Appl. Energy 84, 1258–1273 (2007). https://doi.org/10.1016/j.apenergy.2007.02.005
  33. W. Shi, E.J. Maginn, Molecular simulation of ammonia absorption in the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([emim][Tf2N]). AlChE. J. 55, 2414–2421 (2009). https://doi.org/10.1002/aic.11910
  34. J. Palomar, M. Gonzalez-Miquel, J. Bedia, F. Rodriguez, J.J. Rodriguez, Task-specific ionic liquids for efficient ammonia absorption. Sep. Purif. Technol. 82, 43–52 (2011). https://doi.org/10.1016/j.seppur.2011.08.014
  35. J. Bedia, J. Palomar, M. Gonzalez-Miquel, F. Rodriguez, J.J. Rodriguez, Screening ionic liquids as suitable ammonia absorbents on the basis of thermodynamic and kinetic analysis. Sep. Purif. Technol. 95, 188–195 (2012). https://doi.org/10.1016/j.seppur.2012.05.006
  36. Z. Li, X. Zhang, H. Dong, X. Zhang, H. Gao et al., Efficient absorption of ammonia with hydroxyl-functionalized ionic liquids. RSC Adv. 5, 81362–81370 (2015). https://doi.org/10.1039/C5RA13730F
  37. M.S. Larrechi, A. Cera-Manjarres, D. Salavera, A. Coronas, Quantitative analysis of the interaction of ammonia with 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate ionic liquid. Understanding the volumetric and transport properties of their mixtures. J. Mol. Liq. 301, 112440 (2020). https://doi.org/10.1016/j.molliq.2020.112440
  38. D. Shang, X. Zhang, S. Zeng, K. Jiang, H. Gao et al., Protic ionic liquid[Bim][NTf2]with strong hydrogen bond donating ability for highly efficient ammonia absorption. Green Chem. 19, 937–945 (2017). https://doi.org/10.1039/c6gc03026b
  39. B. Yang, D. Shang, W. Tu, S. Zeng, L. Bai et al., Studies on the physical properties variations of protic ionic liquid during NH3 absorption. J. Mol. Liq. 296, 111791 (2019). https://doi.org/10.1016/j.molliq.2019.111791
  40. T. Zhao, S. Zeng, Y. Li, Y. Bai, L. Bai et al., Molecular insight into the effect of ion structure and interface behavior on the ammonia absorption by ionic liquids. AlChE. J. 68, e17860 (2022). https://doi.org/10.1002/aic.17860
  41. D. Shang, S. Zeng, X. Zhang, X. Zhang, L. Bai et al., Highly efficient and reversible absorption of NH3 by dual functionalised ionic liquids with protic and Lewis acidic sites. J. Mol. Liq. 312, 113411 (2020). https://doi.org/10.1016/j.molliq.2020.113411
  42. L. Yuan, H. Gao, H. Jiang, S. Zeng, T. Li et al., Experimental and thermodynamic analysis of NH3 absorption in dual-functionalized pyridinium-based ionic liquids. J. Mol. Liq. 323, 114601 (2021). https://doi.org/10.1016/j.molliq.2020.114601
  43. X. Luo, R. Qiu, X. Chen, B. Pei, J. Lin et al., Reversible construction of ionic networks through cooperative hydrogen bonds for efficient ammonia absorption. ACS Sustain. Chem. Eng. 7(11), 9888–9895 (2019). https://doi.org/10.1021/acssuschemeng.9b00554
  44. R. Qiu, X. Luo, L. Yang, J. Li, X. Chen et al., Regulated threshold pressure of reversibly sigmoidal NH3 absorption isotherm with ionic liquids. ACS Sustain. Chem. Eng. 8, 1637–1643 (2020). https://doi.org/10.1021/acssuschemeng.9b06555
  45. D. Deng, X. Deng, K. Li, H. Fang, Protic ionic liquid ethanolamine thiocyanate with multiple sites for highly efficient NH3 uptake and NH3/CO2 separation. Sep. Purif. Technol. 276, 119298 (2021). https://doi.org/10.1016/j.seppur.2021.119298
  46. T. Makino, M. Kanakubo, NH3 absorption in Brønsted acidic imidazolium- and ammonium-based ionic liquids. New J. Chem. 44, 20665–20675 (2020). https://doi.org/10.1039/d0nj04743k
  47. W. Chen, S. Liang, Y. Guo, X. Gui, D. Tang, Investigation on vapor–liquid equilibria for binary systems of metal ion-containing ionic liquid[bmim]Zn2Cl5/NH3 by experiment and modified UNIFAC model. Fluid Phase Equilib. 360, 1–6 (2013). https://doi.org/10.1016/j.fluid.2013.09.011
  48. F.T.U. Kohler, S. Popp, H. Klefer, I. Eckle, C. Schrage et al., Supported ionic liquid phase (SILP) materials for removal of hazardous gas compounds–efficient and irreversible NH3 adsorption. Green Chem. 16, 3560–3568 (2014). https://doi.org/10.1039/C3GC42275E
  49. S. Zeng, L. Liu, D. Shang, J. Feng, H. Dong et al., Efficient and reversible absorption of ammonia by cobalt ionic liquids through Lewis acid–base and cooperative hydrogen bond interactions. Green Chem. 20, 2075–2083 (2018). https://doi.org/10.1039/C8GC00215K
  50. J. Wang, S. Zeng, F. Huo, D. Shang, H. He et al., Metal chloride anion-based ionic liquids for efficient separation of NH3. J. Clean. Prod. 206, 661–669 (2019). https://doi.org/10.1016/j.jclepro.2018.09.192
  51. Z. Cai, J. Zhang, Y. Ma, W. Wu, Y. Cao et al., Chelation-activated multiple-site reversible chemical absorption of ammonia in ionic liquids. AlChE. J. 68, e17632 (2022). https://doi.org/10.1002/aic.17632
  52. L.L. Sze, S. Pandey, S. Ravula, S. Pandey, H. Zhao et al., Ternary deep eutectic solvents tasked for carbon dioxide capture. ACS Sustain. Chem. Eng. 2, 2117–2123 (2014). https://doi.org/10.1021/sc5001594
  53. Y. Li, M.C. Ali, Q. Yang, Z. Zhang, Z. Bao et al., Hybrid deep eutectic solvents with flexible hydrogen-bonded supramolecular networks for highly efficient uptake of NH3. ChemSusChem 10, 3368–3377 (2017). https://doi.org/10.1002/cssc.201701135
  54. F.-Y. Zhong, K. Huang, H.-L. Peng, Solubilities of ammonia in choline chloride plus urea at (298.2–353.2) K and (0–300) kPa. J. Chem. Thermodyn. 129, 5–11 (2019). https://doi.org/10.1016/j.jct.2018.09.020
  55. X. Deng, X. Duan, L. Gong, D. Deng, Ammonia solubility, density, and viscosity of choline chloride–dihydric alcohol deep eutectic solvents. J. Chem. Eng. Data 65, 4845–4854 (2020). https://doi.org/10.1021/acs.jced.0c00386
  56. X. Sun, Q. Wang, S. Wu, X. Zhao, L. Wei et al., Metal chlorides-promoted ammonia absorption of deep eutectic solvent. Int. J. Hydrogen Energy 47(36), 16121–16131 (2022). https://doi.org/10.1016/j.ijhydene.2022.03.101
  57. D. Deng, X. Duan, B. Gao, C. Zhang, X. Deng et al., Efficient and reversible absorption of NH3 by functional azole–glycerol deep eutectic solvents. New J. Chem. 43, 11636–11642 (2019). https://doi.org/10.1039/C9NJ01788G
  58. Y. Cao, J. Zhang, Y. Ma, W. Wu, K. Huang et al., Designing low-viscosity deep eutectic solvents with multiple weak–acidic groups for ammonia separation. ACS Sustain. Chem. Eng. 9, 7352–7360 (2021). https://doi.org/10.1021/acssuschemeng.1c01674
  59. W.-J. Jiang, J.-B. Zhang, Y.-T. Zou, H.-L. Peng, K. Huang, Manufacturing acidities of hydrogen-bond donors in deep eutectic solvents for effective and reversible NH3 capture. ACS Sustain. Chem. Eng. 8, 13408–13417 (2020). https://doi.org/10.1021/acssuschemeng.0c04215
  60. X. Duan, B. Gao, C. Zhang, D. Deng, Solubility and thermodynamic properties of NH3 in choline chloride-based deep eutectic solvents. J. Chem. Thermodyn. 133, 79–84 (2019). https://doi.org/10.1016/j.jct.2019.01.031
  61. F.-Y. Zhong, H.-L. Peng, D.-J. Tao, P.-K. Wu, J.-P. Fan et al., Phenol-based ternary deep eutectic solvents for highly efficient and reversible absorption of NH3. ACS Sustain. Chem. Eng. 7, 3258–3266 (2019). https://doi.org/10.1021/acssuschemeng.8b05221
  62. F.-Y. Zhong, L. Zhou, J. Shen, Y. Liu, J.-P. Fan et al., Rational design of azole-based deep eutectic solvents for highly efficient and reversible capture of ammonia. ACS Sustain. Chem. Eng. 7, 14170–14179 (2019). https://doi.org/10.1021/acssuschemeng.9b02845
  63. Z.-L. Li, F.-Y. Zhong, J.-Y. Huang, H.-L. Peng, K. Huang, Sugar-based natural deep eutectic solvents as potential absorbents for NH3 capture at elevated temperatures and reduced pressures. J. Mol. Liq. 317, 113992 (2020). https://doi.org/10.1016/j.molliq.2020.113992
  64. O.V. Kazarina, A.N. Petukhov, R.N. Nagrimanov, A.V. Vorotyntsev, M.E. Atlaskina et al., The role of HBA structure of deep eutectic solvents consisted of ethylene glycol and chlorides of a choline family for improving the ammonia capture performance. J. Mol. Liq. 373, 121216 (2023). https://doi.org/10.1016/j.molliq.2023.121216
  65. O.V. Kazarina, A.N. Petukhov, A.V. Vorotyntsev, M.E. Atlaskina, A.A. Atlaskin et al., The way for improving the efficiency of ammonia and carbon dioxide absorption of choline chloride: urea mixtures by modifying a choline cation. Fluid Phase Equilib. 568, 113736 (2023). https://doi.org/10.1016/j.fluid.2023.113736
  66. O.V. Kazarina, V.N. Agieienko, A.N. Petukhov, A.V. Vorotyntsev, M.E. Atlaskina et al., Deep eutectic solvents composed of urea and new salts of a choline family for efficient ammonia absorption. J. Chem. Eng. Data 67, 138–150 (2022). https://doi.org/10.1021/acs.jced.1c00684
  67. J.-Y. Zhang, K. Huang, Densities and viscosities of, and NH3 solubilities in deep eutectic solvents composed of ethylamine hydrochloride and acetamide. J. Chem. Thermodyn. 139, 105883 (2019). https://doi.org/10.1016/j.jct.2019.105883
  68. W.-J. Jiang, F.-Y. Zhong, Y. Liu, K. Huang, Effective and reversible capture of NH3 by ethylamine hydrochloride plus glycerol deep eutectic solvents. ACS Sustain. Chem. Eng. 7, 10552–10560 (2019). https://doi.org/10.1021/acssuschemeng.9b01102
  69. W.-J. Jiang, F.-Y. Zhong, L.-S. Zhou, H.-L. Peng, J.-P. Fan et al., Chemical dual-site capture of NH3 by unprecedentedly low-viscosity deep eutectic solvents. Chem. Commun. 56, 2399–2402 (2020). https://doi.org/10.1039/C9CC09043F
  70. N.-N. Cheng, Z.-L. Li, H.-C. Lan, W.-L. Xu, W.-J. Jiang et al., Deep eutectic solvents with multiple weak acid sites for highly efficient, reversible and selective absorption of ammonia. Sep. Purif. Technol. 269, 118791 (2021). https://doi.org/10.1016/j.seppur.2021.118791
  71. L. Zheng, X. Zhang, Q. Li, Y. Ma, Z. Cai et al., Effective ammonia separation by non-chloride deep eutectic solvents composed of dihydroxybenzoic acids and ethylene glycol through multiple-site interaction. Sep. Purif. Technol. 309, 123136 (2023). https://doi.org/10.1016/j.seppur.2023.123136
  72. A.I. Akhmetshina, A.N. Petukhov, A. Mechergui, A.V. Vorotyntsev, A.V. Nyuchev et al., Evaluation of methanesulfonate-based deep eutectic solvent for ammonia sorption. J. Chem. Eng. Data 63, 1896–1904 (2018). https://doi.org/10.1021/acs.jced.7b01004
  73. Y. Cao, X. Zhang, S. Zeng, Y. Liu, H. Dong et al., Protic ionic liquid-based deep eutectic solvents with multiple hydrogen bonding sites for efficient absorption of NH3. AIChE J. 66(8), e16253 (2020). https://doi.org/10.1002/aic.16253
  74. Z.-L. Li, F.-Y. Zhong, L.-S. Zhou, Z.-Q. Tian, K. Huang, Deep eutectic solvents formed by N-methylacetamide and heterocyclic weak acids for highly efficient and reversible chemical absorption of ammonia. Ind. Eng. Chem. Res. 59, 2060–2067 (2020). https://doi.org/10.1021/acs.iecr.9b04924
  75. D. Deng, B. Gao, C. Zhang, X. Duan, Y. Cui et al., Investigation of protic NH4SCN− based deep eutectic solvents as highly efficient and reversible NH3 absorbents. Chem. Eng. J. 358, 936–943 (2019). https://doi.org/10.1016/j.cej.2018.10.077
  76. D. Deng, X. Deng, X. Duan, L. Gong, Protic guanidine isothiocyanate plus acetamide deep eutectic solvents with low viscosity for efficient NH3 capture and NH3/CO2 separation. J. Mol. Liq. 324, 114719 (2021). https://doi.org/10.1016/j.molliq.2020.114719
  77. B. Han, C. Butterly, W. Zhang, J.-Z. He, D. Chen, Adsorbent materials for ammonium and ammonia removal: a review. J. Clean. Prod. 283, 124611 (2021). https://doi.org/10.1016/j.jclepro.2020.124611
  78. N.Z. Mohd Azmi, A. Buthiyappan, A.A. Abdul Raman, M.F. Abdul Patah, S. Sufian, Recent advances in biomass based activated carbon for carbon dioxide capture—a review. J. Ind. Eng. Chem. 116, 1–20 (2022). https://doi.org/10.1016/j.jiec.2022.08.021
  79. F. Zhu, Z. Wang, J. Huang, W. Hu, D. Xie et al., Efficient adsorption of ammonia on activated carbon from hydrochar of pomelo peel at room temperature: role of chemical components in feedstock. J. Clean. Prod. 406, 137076 (2023). https://doi.org/10.1016/j.jclepro.2023.137076
  80. C. Cardenas, L. Sigot, C. Vallières, S. Marsteau, M. Marchal et al., Ammonia capture by adsorption on doped and undoped activated carbon: isotherm and breakthrough curve measurements. Sep. Purif. Technol. 313, 123454 (2023). https://doi.org/10.1016/j.seppur.2023.123454
  81. T. Zhang, H. Miyaoka, H. Miyaoka, T. Ichikawa, Y. Kojima, Review on ammonia absorption materials: metal hydrides, halides, and borohydrides. ACS Appl. Energy Mater. 1, 232–242 (2018). https://doi.org/10.1021/acsaem.7b00111
  82. J. Kim, H. Lee, H.T. Vo, G. Lee, N. Kim et al., Bead-shaped mesoporous alumina adsorbents for adsorption of ammonia. Materials (Basel) 13, 1375 (2020). https://doi.org/10.3390/ma13061375
  83. W. Zheng, J. Hu, S. Rappeport, Z. Zheng, Z. Wang et al., Activated carbon fiber composites for gas phase ammonia adsorption. Microporous Mesoporous Mater. 234, 146–154 (2016). https://doi.org/10.1016/j.micromeso.2016.07.011
  84. C. Li, S. Zhao, M. Li, Z. Yao, Y. Li et al., The effect of the active carbonyl groups and residual acid on the ammonia adsorption over the acid-modified activated carbon. Front. Environ. Sci. 11, 976113 (2023). https://doi.org/10.3389/fenvs.2023.976113
  85. W. Zhang, F. Liu, X. Kan, Y. Zheng, A. Zheng et al., Developing ordered mesoporous silica superacids for high-precision adsorption and separation of ammonia. Chem. Eng. J. 457, 141263 (2023). https://doi.org/10.1016/j.cej.2022.141263
  86. I. Matito-Martos, A. Martin-Calvo, C.O. Ania, J.B. Parra, J.M. Vicent-Luna et al., Role of hydrogen bonding in the capture and storage of ammonia in zeolites. Chem. Eng. J. 387, 124062 (2020). https://doi.org/10.1016/j.cej.2020.124062
  87. W. Ouyang, S. Zheng, C. Wu, X. Hu, R. Chen et al., Dynamic ammonia adsorption by FAU zeolites to below 0.1 ppm for hydrogen energy applications. Int. J. Hydrog. Energy 46, 32559–32569 (2021). https://doi.org/10.1016/j.ijhydene.2021.07.107
  88. J.M. Lucero, J.M. Crawford, C.A. Wolden, M.A. Carreon, Tunability of ammonia adsorption over NaP zeolite. Microporous Mesoporous Mater. 324, 111288 (2021). https://doi.org/10.1016/j.micromeso.2021.111288
  89. B. Zhakisheva, J.J. Gutiérrez-Sevillano, S. Calero, Ammonia and water in zeolites: effect of aluminum distribution on the heat of adsorption. Sep. Purif. Technol. 306, 122564 (2023). https://doi.org/10.1016/j.seppur.2022.122564
  90. C. Shen, L. Shen, Cyclic NH3 adsorption–desorption characteristics of Cu-based metal halides as ammonia separation and storage procedure. J. Energy Inst. 109, 101250 (2023). https://doi.org/10.1016/j.joei.2023.101250
  91. Z. Cao, F. Akhtar, Porous strontium chloride scaffolded by graphene networks as ammonia carriers. Adv. Funct. Mater. 31, 2008505 (2021). https://doi.org/10.1002/adfm.202008505
  92. T. Zhu, B. Pei, T. Di, Y. Xia, T. Li et al., Thirty-minute preparation of microporous polyimides with large surface areas for ammonia adsorption. Green Chem. 22, 7003–7009 (2020). https://doi.org/10.1039/d0gc02794d
  93. Y.-S. Han, S. An, J. Dai, J. Hu, Q. Xu et al., Defect-engineering of anionic porous aromatic frameworks for ammonia capture. ACS Appl. Polym. Mater. 3, 4534–4542 (2021). https://doi.org/10.1021/acsapm.1c00589
  94. J.F. Van Humbeck, T.M. McDonald, X. Jing, B.M. Wiers, G. Zhu et al., Ammonia capture in porous organic polymers densely functionalized with Brønsted acid groups. J. Am. Chem. Soc. 136, 2432–2440 (2014). https://doi.org/10.1021/ja4105478
  95. J. Zhang, Y. Ma, W. Wu, Z. Cai, Y. Cao et al., Carboxylic functionalized mesoporous polymers for fast, highly efficient, selective and reversible adsorption of ammonia. Chem. Eng. J. 448, 137640 (2022). https://doi.org/10.1016/j.cej.2022.137640
  96. D. Jung, Z. Chen, S. Alayoglu, M.R. Mian, T.A. Goetjen et al., Postsynthetically modified polymers of intrinsic microporosity (PIMs) for capturing toxic gases. ACS Appl. Mater. Interfaces 13, 10409–10415 (2021). https://doi.org/10.1021/acsami.0c21741
  97. C.-C. Hsieh, J.-S. Tsai, J.-R. Chang, Effects of moisture on NH3 Capture using activated carbon and acidic porous polymer modified by impregnation with H3PO4: sorbent material characterized by synchrotron XRPD and FT-IR. Materials (Basel) 15, 784 (2022). https://doi.org/10.3390/ma15030784
  98. G. Barin, G.W. Peterson, V. Crocellà, J. Xu, K.A. Colwell et al., Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations. Chem. Sci. 8, 4399–4409 (2017). https://doi.org/10.1039/c6sc05079d
  99. Z. Han, Y. Mao, X. Pang, Y. Yan, Structure and functional group regulation of plastics for efficient ammonia capture. J. Hazard. Mater. 440, 129789 (2022). https://doi.org/10.1016/j.jhazmat.2022.129789
  100. J. Mi, W. Peng, Y. Luo, W. Chen, L. Lin et al., A cationic polymerization strategy to design sulfonated micro–mesoporous polymers as efficient adsorbents for ammonia capture and separation. Macromolecules 54, 7010–7020 (2021). https://doi.org/10.1021/acs.macromol.1c00376
  101. X. Kan, Z. Liu, F. Liu, F. Li, W. Chen et al., Sulfonated and ordered mesoporous polymers for reversible adsorption of ammonia: elucidation of sequential pore-space diffusion. Chem. Eng. J. 451, 139085 (2023). https://doi.org/10.1016/j.cej.2022.139085
  102. D.W. Kang, M. Kang, M. Moon, H. Kim, S. Eom et al., PDMS-coated hypercrosslinked porous organic polymers modified via double postsynthetic acidifications for ammonia capture. Chem. Sci. 9, 6871–6877 (2018). https://doi.org/10.1039/c8sc02640h
  103. D.W. Kang, M. Kang, D.W. Kim, H. Kim, Y.H. Lee et al., Engineered removal of trace NH3 by porous organic polymers modified via sequential post-sulfonation and post-alkylation. Adv. Sustain. Syst. 5, 2000161 (2021). https://doi.org/10.1002/adsu.202000161
  104. R.J.S. Lima, D.V. Okhrimenko, S. Rudić, M.T.F. Telling, V.G. Sakai et al., Ammonia storage in hydrogen bond-rich microporous polymers. ACS Appl. Mater. Interfaces 12, 58161–58169 (2020). https://doi.org/10.1021/acsami.0c18855
  105. J.-W. Lee, G. Barin, G.W. Peterson, J. Xu, K.A. Colwell et al., A microporous amic acid polymer for enhanced ammonia capture. ACS Appl. Mater. Interfaces 9, 33504–33510 (2017). https://doi.org/10.1021/acsami.7b02603
  106. L. Luo, J. Li, X. Chen, X. Cao, Y. Liu et al., Superhigh and reversible NH3 uptake of cobaltous thiocyanate functionalized porous poly ionic liquids through competitive and cooperative interactions. Chem. Eng. J. 427, 131638 (2022). https://doi.org/10.1016/j.cej.2021.131638
  107. L. Luo, Z. Wu, Z. Wu, Y. Liu, X. Huang et al., Role of structure in the ammonia uptake of porous polyionic liquids. ACS Sustain. Chem. Eng. 10, 4094–4104 (2022). https://doi.org/10.1021/acssuschemeng.1c06503
  108. D.W. Kang, S.E. Ju, D.W. Kim, M. Kang, H. Kim et al., Emerging porous materials and their composites for NH3 gas removal. Adv. Sci. 7, 2002142 (2020). https://doi.org/10.1002/advs.202002142
  109. M.-S. Yao, W.-H. Li, G. Xu, Metal–organic frameworks and their derivatives for electrically-transduced gas sensors. Coord. Chem. Rev. 426, 213479 (2021). https://doi.org/10.1016/j.ccr.2020.213479
  110. M.-S. Yao, K.-I. Otake, J. Zheng, M. Tsujimoto, Y.-F. Gu et al., Integrated soft porosity and electrical properties of conductive-on-insulating metal–organic framework nanocrystals. Angew. Chem. Int. Ed. 62, e202303903 (2023). https://doi.org/10.1002/anie.202303903
  111. Y. Gao, J. Wang, Y. Yang, J. Wang, C. Zhang et al., Engineering spin states of isolated copper species in a metal–organic framework improves urea electrosynthesis. Nano-Micro Lett. 15, 158 (2023). https://doi.org/10.1007/s40820-023-01127-0
  112. C. Li, Y. Ji, Y. Wang, C. Liu, Z. Chen et al., Applications of metal–organic frameworks and their derivatives in electrochemical CO2 reduction. Nano-Micro Lett. 15, 113 (2023). https://doi.org/10.1007/s40820-023-01092-8
  113. A. Takahashi, H. Tanaka, D. Parajuli, T. Nakamura, K. Minami et al., Historical pigment exhibiting ammonia gas capture beyond standard adsorbents with adsorption sites of two kinds. J. Am. Chem. Soc. 138, 6376–6379 (2016). https://doi.org/10.1021/jacs.6b02721
  114. A.J. Rieth, M. Dincă, Controlled gas uptake in metal–organic frameworks with record ammonia sorption. J. Am. Chem. Soc. 140, 3461–3466 (2018). https://doi.org/10.1021/jacs.8b00313
  115. A. Carné-Sánchez, J. Martínez-Esaín, T. Rookard, C.J. Flood, J. Faraudo et al., Ammonia capture in rhodium(II)-based metal–organic polyhedra via synergistic coordinative and H-bonding interactions. ACS Appl. Mater. Interfaces 15, 6747–6754 (2023). https://doi.org/10.1021/acsami.2c19206
  116. D. Zhang, Y. Shen, J. Ding, H. Zhou, Y. Zhang et al., Tunable ammonia adsorption within metal–organic frameworks with different unsaturated metal sites. Molecules 27, 7847 (2022). https://doi.org/10.3390/molecules27227847
  117. S. Moribe, Z. Chen, S. Alayoglu, Z.H. Syed, T. Islamoglu et al., Ammonia capture within isoreticular metal–organic frameworks with rod secondary building units. ACS Mater. Lett. 1, 476–480 (2019). https://doi.org/10.1021/acsmaterialslett.9b00307
  118. K.O. Kirlikovali, Z. Chen, X. Wang, M.R. Mian, S. Alayoglu et al., Investigating the influence of hexanuclear clusters in isostructural metal–organic frameworks on toxic gas adsorption. ACS Appl. Mater. Interfaces 14, 3048–3056 (2022). https://doi.org/10.1021/acsami.1c20518
  119. D.W. Kim, D.W. Kang, M. Kang, J.H. Lee, J.H. Choe et al., High ammonia uptake of a metal–organic framework adsorbent in a wide pressure range. Angew. Chem. Int. Ed. 59, 22531–22536 (2020). https://doi.org/10.1002/anie.202012552
  120. T.N. Nguyen, I.M. Harreschou, J.-H. Lee, K.C. Stylianou, D.W. Stephan, A recyclable metal–organic framework for ammonia vapour adsorption. Chem. Commun. 56, 9600–9603 (2020). https://doi.org/10.1039/d0cc00741b
  121. C. Marsh, X. Han, J. Li, Z. Lu, S.P. Argent et al., Exceptional packing density of ammonia in a dual-functionalized metal–organic framework. J. Am. Chem. Soc. 143, 6586–6592 (2021). https://doi.org/10.1021/jacs.1c01749
  122. Z. Fang, B. Bueken, D.E. De Vos, R.A. Fischer, Defect-engineered metal–organic frameworks. Angew. Chem. Int. Ed. 54, 7234–7254 (2015). https://doi.org/10.1002/anie.201411540
  123. J. Ren, M. Ledwaba, N.M. Musyoka, H.W. Langmi, M. Mathe et al., Structural defects in metal–organic frameworks (MOFs): formation, detection and control towards practices of interests. Coord. Chem. Rev. 349, 169–197 (2017). https://doi.org/10.1016/j.ccr.2017.08.017
  124. Q.-Y. Ju, J.-J. Zheng, L. Xu, H.-Y. Jiang, Z.-Q. Xue et al., Enhanced carbon capture with motif-rich amino acid loaded defective robust metal–organic frameworks. Nano Res. 17, 2004–2010 (2024). https://doi.org/10.1007/s12274-023-5961-y
  125. Y. Ma, W. Lu, X. Han, Y. Chen, I. da Silva et al., Direct observation of ammonia storage in UiO-66 incorporating Cu(II) binding sites. J. Am. Chem. Soc. 144, 8624–8632 (2022). https://doi.org/10.1021/jacs.2c00952
  126. G.W. Peterson, G.W. Wagner, A. Balboa, J. Mahle, T. Sewell et al., Ammonia vapor removal by Cu(3)(BTC)(2) and its characterization by MAS NMR. J. Phys. Chem. C Nanomater. Interfaces 113, 13906–13917 (2009). https://doi.org/10.1021/jp902736z
  127. C. Bae, M. Gu, Y. Jeon, D. Kim, J. Kim, Metal–organic frameworks for NH3 adsorption by different NH3 operating pressures. Bull. Korean Chem. Soc. 44(2), 112–124 (2022). https://doi.org/10.1002/bkcs.12640
  128. J.H. Carter, C.G. Morris, H.G.W. Godfrey, S.J. Day, J. Potter et al., Long-term stability of MFM-300(Al) toward toxic air pollutants. ACS Appl. Mater. Interfaces 12, 42949–42954 (2020). https://doi.org/10.1021/acsami.0c11134
  129. H.G.W. Godfrey, I. da Silva, L. Briggs, J.H. Carter, C.G. Morris et al., Ammonia storage by reversible host-guest site exchange in a robust metal–organic framework. Angew. Chem. Int. Ed. 57, 14778–14781 (2018). https://doi.org/10.1002/anie.201808316
  130. X. Han, W. Lu, Y. Chen, I. da Silva, J. Li et al., High ammonia adsorption in MFM-300 materials: dynamics and charge transfer in host-guest binding. J. Am. Chem. Soc. 143, 3153–3161 (2021). https://doi.org/10.1021/jacs.0c11930
  131. Z. Wang, Z. Li, H. Wang, Y. Zhao, Q. Xia et al., Regulating the pore microenvironment of microporous metal–organic frameworks for efficient adsorption of low-concentration ammonia. ACS Sustain. Chem. Eng. 10, 10945–10954 (2022). https://doi.org/10.1021/acssuschemeng.2c02944
  132. J.H. Lee, S. Jeoung, Y.G. Chung, H.R. Moon, Elucidation of flexible metal–organic frameworks: research progresses and recent developments. Coord. Chem. Rev. 389, 161–188 (2019). https://doi.org/10.1016/j.ccr.2019.03.008
  133. I. Senkovska, V. Bon, L. Abylgazina, M. Mendt, J. Berger et al., Understanding MOF flexibility: an analysis focused on pillared layer MOFs as a model system. Angew. Chem. Int. Ed. 62, e202218076 (2023). https://doi.org/10.1002/anie.202218076
  134. Y. Chen, B. Shan, C. Yang, J. Yang, J. Li et al., Environmentally friendly synthesis of flexible MOFs M(NA)2 (M = Zn Co, Cu, Cd) with large and regenerable ammonia capacity. J. Mater. Chem. A 6, 9922–9929 (2018). https://doi.org/10.1039/C8TA02845A
  135. D.W. Kang, M. Kang, H. Kim, J.H. Choe, D.W. Kim et al., A hydrogen-bonded organic framework (HOF) with type IV NH3 adsorption behavior. Angew. Chem. Int. Ed. 58, 16152–16155 (2019). https://doi.org/10.1002/anie.201911087
  136. X. Song, Y. Wang, C. Wang, X. Gao, Y. Zhou et al., Self-healing hydrogen-bonded organic frameworks for low-concentration ammonia capture. J. Am. Chem. Soc. 146, 627–634 (2024). https://doi.org/10.1021/jacs.3c10492
  137. J. Li, L. Luo, L. Yang, C. Zhao, Y. Liu et al., Ionic framework constructed with protic ionic liquid units for improving ammonia uptake. Chem. Commun. 57, 4384–4387 (2021). https://doi.org/10.1039/d1cc00441g
  138. C.J. Doonan, D.J. Tranchemontagne, T.G. Glover, J.R. Hunt, O.M. Yaghi, Exceptional ammonia uptake by a covalent organic framework. Nat. Chem. 2, 235–238 (2010). https://doi.org/10.1038/nchem.548
  139. Y. Cao, R. Wu, Y.-Y. Gao, Y. Zhou, J.-J. Zhu, Advances of electrochemical and electrochemiluminescent sensors based on covalent organic frameworks. Nano-Micro Lett. 16, 37 (2023). https://doi.org/10.1007/s40820-023-01249-5
  140. Y. Yang, M. Faheem, L. Wang, Q. Meng, H. Sha et al., Surface pore engineering of covalent organic frameworks for ammonia capture through synergistic multivariate and open metal site approaches. ACS Cent. Sci. 4, 748–754 (2018). https://doi.org/10.1021/acscentsci.8b00232
  141. Y. Zhao, S. Zhang, L. Wu, C. Guo, X. Song, Multiscale study on ammonia adsorption by Li-doped COF-10. Comput. Theor. Chem. 1175, 112744 (2020). https://doi.org/10.1016/j.comptc.2020.112744
  142. Z. Zhu, H. Wang, X.-Y. Wu, K. Luo, J. Fan, Computational screening of metal–organic frameworks for ammonia capture from H2/N2/NH3 mixtures. ACS Omega 7, 37640–37653 (2022). https://doi.org/10.1021/acsomega.2c04517
  143. Y. Khabzina, D. Farrusseng, Unravelling ammonia adsorption mechanisms of adsorbents in humid conditions. Microporous Mesoporous Mater. 265, 143–148 (2018). https://doi.org/10.1016/j.micromeso.2018.02.011
  144. R. Chen, J. Liu, Competitive coadsorption of ammonia with water and sulfur dioxide on metal–organic frameworks at low pressure. Build. Environ. 207, 108421 (2022). https://doi.org/10.1016/j.buildenv.2021.108421
  145. C. Shen, P. Wang, L. Shen, X. Yin, Z. Miao, NH3 adsorption performance of silicon-supported metal chlorides. Ind. Eng. Chem. Res. 61, 8616–8623 (2022). https://doi.org/10.1021/acs.iecr.2c00916
  146. C. Shen, L. Shen, XCl2/MWCNTs─Composites based on multi-walled carbon nanotubes and metal chlorides for NH3 capture and separation. Energy Fuels 37, 5995–6001 (2023). https://doi.org/10.1021/acs.energyfuels.3c00467
  147. X. Tian, J. Qiu, Z. Wang, Y. Chen, Z. Li et al., A record ammonia adsorption by calcium chloride confined in covalent organic frameworks. Chem. Commun. 58, 1151–1154 (2022). https://doi.org/10.1039/D1CC06308A
  148. Y. Jian, W. Hu, Z. Zhao, P. Cheng, H. Haick et al., Gas sensors based on chemi-resistive hybrid functional nanomaterials. Nano-Micro Lett. 12, 71 (2020). https://doi.org/10.1007/s40820-020-0407-5
  149. K.N. Ruckart, Y. Zhang, W.M. Reichert, G.W. Peterson, T.G. Glover, Sorption of ammonia in mesoporous-silica ionic liquid composites. Ind. Eng. Chem. Res. 55, 12191–12204 (2016). https://doi.org/10.1021/acs.iecr.6b02041
  150. A. Kaftan, H. Klefer, M. Haumann, M. Laurin, P. Wasserscheid et al., An operando DRIFTS-MS study of NH3 removal by supported ionic liquid phase (SILP) materials. Sep. Purif. Technol. 174, 245–250 (2017). https://doi.org/10.1016/j.seppur.2016.10.017
  151. M. Yu, S. Zeng, Z. Wang, Z. Hu, H. Dong et al., Protic ionic-liquid-supported activated carbon with hierarchical pores for efficient NH3 adsorption. ACS Sustain. Chem. Eng. 7, 11769–11777 (2019). https://doi.org/10.1021/acssuschemeng.9b02051
  152. Y. Li, S. Zeng, S. Zheng, T. Zhao, X. Sun et al., Mesoporous multiproton ionic liquid hybrid adsorbents for facilitating NH3 separation. Ind. Eng. Chem. Res. 62, 2829–2842 (2023). https://doi.org/10.1021/acs.iecr.2c03193
  153. S. Zheng, Q. Xu, S. Zeng, G. Li, H. Jiang et al., Porous multi-site ionic liquid composites for superior selective and reversible adsorption of ammonia. Sep. Purif. Technol. 310, 123161 (2023). https://doi.org/10.1016/j.seppur.2023.123161
  154. D. Cao, Z. Li, Z. Wang, H. Wang, S. Gao et al., Highly dispersed ionic liquids in mesoporous molecular sieves enable a record NH3 absorption. ACS Sustain. Chem. Eng. 9, 16363–16372 (2021). https://doi.org/10.1021/acssuschemeng.1c06151
  155. S. Zeng, J. Wang, P. Li, H. Dong, H. Wang et al., Efficient adsorption of ammonia by incorporation of metal ionic liquids into silica gels as mesoporous composites. Chem. Eng. J. 370, 81–88 (2019). https://doi.org/10.1016/j.cej.2019.03.180
  156. G. Han, C. Liu, Q. Yang, D. Liu, C. Zhong, Construction of stable IL@MOF composite with multiple adsorption sites for efficient ammonia capture from dry and humid conditions. Chem. Eng. J. 401, 126106 (2020). https://doi.org/10.1016/j.cej.2020.126106
  157. G. Han, F. Li, M. Guo, H. Fan, Q. Guo et al., MIL-101(Cr) loaded simple ILs for efficient ammonia capture and selective separation. Chem. Eng. J. 471, 144545 (2023). https://doi.org/10.1016/j.cej.2023.144545
  158. Y. Shi, Z. Wang, Z. Li, H. Wang, D. Xiong et al., Anchoring LiCl in the nanopores of metal–organic frameworks for ultra-high uptake and selective separation of ammonia. Angew. Chem. Int. Ed. 61, e202212032 (2022). https://doi.org/10.1002/anie.202212032
  159. Q. Luo, E. Pentzer, Encapsulation of ionic liquids for tailored applications. ACS Appl. Mater. Interfaces 12, 5169–5176 (2020). https://doi.org/10.1021/acsami.9b16546
  160. R. Santiago, J. Lemus, D. Moreno, C. Moya, M. Larriba et al., From kinetics to equilibrium control in CO2 capture columns using Encapsulated Ionic Liquids (ENILs). Chem. Eng. J. 348, 661–668 (2018). https://doi.org/10.1016/j.cej.2018.05.029
  161. S. Zheng, S. Zeng, Y. Li, L. Bai, Y. Bai et al., State of the art of ionic liquid-modified adsorbents for CO2 capture and separation. AlChE. J. 68, e17500 (2022). https://doi.org/10.1002/aic.17500
  162. J. Palomar, J. Lemus, N. Alonso-Morales, J. Bedia, M.A. Gilarranz et al., Encapsulated ionic liquids (ENILs): from continuous to discrete liquid phase. Chem. Commun. 48, 10046–10048 (2012). https://doi.org/10.1039/C2CC35291E
  163. J. Lemus, J. Bedia, C. Moya, N. Alonso-Morales, M.A. Gilarranz et al., Ammonia capture from the gas phase by encapsulated ionic liquids (ENILs). RSC Adv. 6, 61650–61660 (2016). https://doi.org/10.1039/C6RA11685J
  164. N. O’Reilly, N. Giri, S.L. James, Porous liquids. Chem. Eur. J. 13(11), 3020–3025 (2007). https://doi.org/10.1002/chem.200700090
  165. N. Giri, M.G. Del Pópolo, G. Melaugh, R.L. Greenaway, K. Rätzke et al., Liquids with permanent porosity. Nature 527, 216–220 (2015). https://doi.org/10.1038/nature16072
  166. K. Jie, Y. Zhou, H.P. Ryan, S. Dai, J.R. Nitschke, Engineering permanent porosity into liquids. Adv. Mater. 33, 2005745 (2021). https://doi.org/10.1002/adma.202005745
  167. J. Zhang, S.-H. Chai, Z.-A. Qiao, S.M. Mahurin, J. Chen et al., Porous liquids: a promising class of media for gas separation. Angew. Chem. Int. Ed. 54, 932–936 (2015). https://doi.org/10.1002/anie.201409420
  168. W. Shan, P.F. Fulvio, L. Kong, J.A. Schott, C.-L. Do-Thanh et al., New class of type III porous liquids: a promising platform for rational adjustment of gas sorption behavior. ACS Appl. Mater. Interfaces 10, 32–36 (2018). https://doi.org/10.1021/acsami.7b15873
  169. B.D. Egleston, K.V. Luzyanin, M.C. Brand, R. Clowes, M.E. Briggs et al., Controlling gas selectivity in molecular porous liquids by tuning the cage window size. Angew. Chem. Int. Ed. 59, 7362–7366 (2020). https://doi.org/10.1002/anie.201914037
  170. D.P. Erdosy, M.B. Wenny, J. Cho, C. DelRe, M.V. Walter et al., Microporous water with high gas solubilities. Nature 608, 712–718 (2022). https://doi.org/10.1038/s41586-022-05029-w
  171. N. Giri, C.E. Davidson, G. Melaugh, M.G. Del Pópolo, J.T.A. Jones et al., Alkylated organic cages: from porous crystals to neat liquids. Chem. Sci. 3, 2153 (2012). https://doi.org/10.1039/c2sc01007k
  172. T.D. Bennett, F.-X. Coudert, S.L. James, A.I. Cooper, The changing state of porous materials. Nat. Mater. 20, 1179–1187 (2021). https://doi.org/10.1038/s41563-021-00957-w
  173. R. Gaillac, P. Pullumbi, K.A. Beyer, K.W. Chapman, D.A. Keen et al., Liquid metal–organic frameworks. Nat. Mater. 16, 1149–1154 (2017). https://doi.org/10.1038/nmat4998
  174. S. Liu, J. Liu, X. Hou, T. Xu, J. Tong et al., Porous liquid: a stable ZIF-8 colloid in ionic liquid with permanent porosity. Langmuir 34, 3654–3660 (2018). https://doi.org/10.1021/acs.langmuir.7b04212
  175. D.S. Sholl, R.P. Lively, Seven chemical separations to change the world. Nature 532, 435–437 (2016). https://doi.org/10.1038/532435a
  176. D.L. Gin, R.D. Noble, Designing the next generation of chemical separation membranes. Science 332, 674–676 (2011). https://doi.org/10.1126/science.1203771
  177. H. Wang, J. Zhao, Y. Li, Y. Cao, Z. Zhu et al., Aqueous two-phase interfacial assembly of COF membranes for water desalination. Nano-Micro Lett. 14, 216 (2022). https://doi.org/10.1007/s40820-022-00968-5
  178. I.V. Vorotyntsev, P.N. Drozdov, N.V. Karyakin, Ammonia permeability of a cellulose acetate membrane. Inorg. Mater. 42, 231–235 (2006). https://doi.org/10.1134/S0020168506030034
  179. C. Makhloufi, D. Roizard, E. Favre, Reverse selective NH3/CO2 permeation in fluorinated polymers using membrane gas separation. J. Membr. Sci. 441, 63–72 (2013). https://doi.org/10.1016/j.memsci.2013.03.048
  180. A.V. Vorobiev, I.N. Beckman, Ammonia and carbon dioxide permeability through perfluorosulfonic membranes. Russ. Chem. Bull. 51, 275–281 (2002). https://doi.org/10.1023/A:1015403626398
  181. W.A. Phillip, E. Martono, L. Chen, M.A. Hillmyer, E.L. Cussler, Seeking an ammonia selective membrane based on nanostructured sulfonated block copolymers. J. Membr. Sci. 337, 39–46 (2009). https://doi.org/10.1016/j.memsci.2009.03.013
  182. L. Ansaloni, Z. Dai, J.J. Ryan, K.P. Mineart, Q. Yu et al., Solvent-templated Block ionomers for base- and acid-gas separations: effect of humidity on ammonia and carbon dioxide permeation. Adv. Mater. Interfaces 4, 1700854 (2017). https://doi.org/10.1002/admi.201700854
  183. K. Wakimoto, W.-W. Yan, N. Moriyama, H. Nagasawa, M. Kanezashi et al., Ammonia permeation of fluorinated sulfonic acid polymer/ceramic composite membranes. J. Membr. Sci. 658, 120718 (2022). https://doi.org/10.1016/j.memsci.2022.120718
  184. B. Yang, L. Bai, Z. Wang, H. Jiang, S. Zeng et al., Exploring NH3 transport properties by tailoring ionic liquids in pebax-based hybrid membranes. Ind. Eng. Chem. Res. 60, 9570–9577 (2021). https://doi.org/10.1021/acs.iecr.1c01408
  185. H. Jiang, L. Bai, K. Peng, L. Yuan, S. Zheng et al., Blended membranes with ionic liquids tailoring by hydroxyl group for efficient NH3 separation. J. Membr. Sci. 674, 121480 (2023). https://doi.org/10.1016/j.memsci.2023.121480
  186. B. Yang, L. Bai, T. Li, L. Deng, L. Liu et al., Super selective ammonia separation through multiple-site interaction with ionic liquid-based hybrid membranes. J. Membr. Sci. 628, 119264 (2021). https://doi.org/10.1016/j.memsci.2021.119264
  187. B. Yang, L. Bai, S. Zeng, S. Luo, L. Liu et al., NH3 separation membranes with self-assembled gas highways induced by protic ionic liquids. Chem. Eng. J. 421, 127876 (2021). https://doi.org/10.1016/j.cej.2020.127876
  188. Z. Wang, H. Dong, X. Yu, Y. Ji, T. Hou et al., Two-dimensional porous polyphthalocyanine (PPc) as an efficient gas-separation membrane for ammonia synthesis. Curr. Appl. Phys. 17, 1765–1770 (2017). https://doi.org/10.1016/j.cap.2017.08.019
  189. I.I. Zaripov, I.M. Davletbaeva, Z.Z. Faizulina, R.S. Davletbaev, A.T. Gubaidullin et al., Synthesis and characterization of novel nanoporous gl-POSS-branched polymeric gas separation membranes. Membranes 10, 110 (2020). https://doi.org/10.3390/membranes10050110
  190. M. Kanezashi, A. Yamamoto, T. Yoshioka, T. Tsuru, Characteristics of ammonia permeation through porous silica membranes. AlChE. J. 56, 1204–1212 (2010). https://doi.org/10.1002/aic.12059
  191. O. Camus, S. Perera, B. Crittenden, Y.C. van Delft, D.F. Meyer et al., Ceramic membranes for ammonia recovery. AlChE. J. 52, 2055–2065 (2006). https://doi.org/10.1002/aic.10800
  192. H. Inami, C. Abe, Y. Hasegawa, Development of ammonia selectively permeable zeolite membrane for sensor in sewer system. Membranes 11, 348 (2021). https://doi.org/10.3390/membranes11050348
  193. D.I. Petukhov, A.S. Kan, A.P. Chumakov, O.V. Konovalov, R.G. Valeev et al., MXene-based gas separation membranes with sorption type selectivity. J. Membr. Sci. 621, 118994 (2021). https://doi.org/10.1016/j.memsci.2020.118994
  194. M.A. Komkova, I.S. Sadilov, V.A. Brotsman, D.I. Petukhov, A.A. Eliseev, Facilitated transport of ammonia in ultra-thin Prussian Blue membranes with potential-tuned selectivity. J. Membr. Sci. 639, 119714 (2021). https://doi.org/10.1016/j.memsci.2021.119714
  195. Q. Wei, J.M. Lucero, J.M. Crawford, J.D. Way, C.A. Wolden et al., Ammonia separation from N2 and H2 over LTA zeolitic imidazolate framework membranes. J. Membr. Sci. 623, 119078 (2021). https://doi.org/10.1016/j.memsci.2021.119078
  196. S. Padinjarekutt, H. Li, S. Ren, P. Ramesh, F. Zhou et al., Na+-gated nanochannel membrane for highly selective ammonia (NH3) separation in the Haber-Bosch process. Chem. Eng. J. 454, 139998 (2023). https://doi.org/10.1016/j.cej.2022.139998
  197. S. Padinjarekutt, B. Sengupta, H. Li, K. Friedman, D. Behera et al., Synthesis of Na+-gated nanochannel membranes for the ammonia (NH3) separation. J. Membr. Sci. 674, 121512 (2023). https://doi.org/10.1016/j.memsci.2023.121512
  198. L. Yu, L. Hao, Y. Feng, J. Pang, M. Guo et al., Assembling ionic liquid into porous molecular filler of mixed matrix membrane to trigger high gas permeability, selectivity, and stability for CO2/CH4 separation. Nano Res. 17, 4535–4543 (2024). https://doi.org/10.1007/s12274-023-6329-z
  199. Y. Wang, Y. Ren, Y. Cao, X. Liang, G. He et al., Engineering HOF-based mixed-matrix membranes for efficient CO2 separation. Nano-Micro Lett. 15, 50 (2023). https://doi.org/10.1007/s40820-023-01020-w
  200. Y. Yang, B. Pang, W. Zeng, B. Ma, P. Yin et al., Enhance gas-separation efficiency of mixed matrix membranes by lamellarly arranged metal–organic polyhedron. Nano Res. 16, 11450–11454 (2023). https://doi.org/10.1007/s12274-023-5874-9
  201. A. Raza, S. Farrukh, A. Hussain, Synthesis, characterization and NH3/N2 gas permeation study of nanocomposite membranes. J. Polym. Environ. 25, 46–55 (2017). https://doi.org/10.1007/s10924-016-0783-6
  202. J.B. DeCoste, M.S. Denny Jr., G.W. Peterson, J.J. Mahle, S.M. Cohen, Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption. Chem. Sci. 7, 2711–2716 (2016). https://doi.org/10.1039/c5sc04368a
  203. H. Jiang, L. Bai, Z. Wang, W. Zheng, B. Yang et al., Mixed matrix membranes containing Cu-based metal organic framework and functionalized ionic liquid for efficient NH3 separation. J. Membr. Sci. 659, 120780 (2022). https://doi.org/10.1016/j.memsci.2022.120780
  204. M.-S. Yao, K.-I. Otake, T. Koganezawa, M. Ogasawara, H. Asakawa et al., Growth mechanisms and anisotropic softness–dependent conductivity of orientation-controllable metal–organic framework nanofilms. Proc. Natl. Acad. Sci. U.S.A. 120, e2305125120 (2023). https://doi.org/10.1073/pnas.2305125120
  205. M.-S. Yao, K.-I. Otake, S. Kitagawa, Interface chemistry of conductive crystalline porous thin films. Trends Chem. 5, 588–604 (2023). https://doi.org/10.1016/j.trechm.2023.03.002
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