Issue

Vol. 3 No. 1 (2011)

Synthesis and Photocatalytic Activity of Fe-doped TiO2 Supported on Hollow Glass Microbeads

https://doi.org/10.1007/BF03353647
Wenyan Zhao
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Wuyou Fu
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Haibin Yang
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Chuanjin Tian
Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, P. R. China
Minghui Li
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Juan Ding
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Wei Zhang
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Xiaoming Zhou
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Hui Zhao
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China
Yixing Li
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China

Corresponding Author: Haibin Yang

yanghb@jlu.edu.cn

Nano-Micro Letters, Vol. 3 No. 1 (2011), Article Number: 20-24

Abstract

In this paper, Fe-doped TiO2 photocatalyst supported on hollow glass microbeads (Fe-TiO2/beads) is prepared by dip-coating method, which uses hollow glass microbeads as the carriers and tetrabutylorthotitanate [Ti(OC4H9)4] as the raw material. The phase structure, ingredient, morphologies, particle size and shell thickness of the products are characterized by X-ray powder diffraction (XRD), energy-dispersive spectroscopy (EDS) and field emission scanning electron microscope (FESEM). The feasibility of photocatylic degradation of Rhodamine B (RhB) under illumination of UV-vis light is studied. The results show that the core-shell structure catalyst is composed of Fe-doped anatase TiO2 and hollow glass microbeads, and the catalytic activity of the TiO2 is markedly enhanced by Fe ion doping. The optimum concentration of Fe ion is 0.1% (molecular fraction) in the precursor and the photocatalytic activity can be increased to 98% compared with that of the undoped one. The presence of ferrum elements neither influences the transformation of anatase to rutile, nor creates new crystal phases. The possible mechanism of photocatalytic oxidation is also discussed.

Keywords

TiO2 Sol-gel method Semiconductor Photocatalytic activity Hollow glass microbeads
Zhao, Wenyan, Wuyou Fu, Haibin Yang, Chuanjin Tian, Minghui Li, Juan Ding, Wei Zhang, Xiaoming Zhou, Hui Zhao, and Yixing Li. 2011. “Synthesis and Photocatalytic Activity of Fe-Doped TiO2 Supported on Hollow Glass Microbeads”. Nano-Micro Letters 3 (1):20-24. https://doi.org/10.1007/BF03353647.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. R. Hoffmann, S. T. Martin, W. Choi and D. W. Bahnemann, Chem. Rev. 95, 69 (1995). http://dx.doi.org/10.1021/cr00033a004
  2. B. Sun, A. V. Vorontsov and P. G. Smirniotis, Langmuir 19, 3151 (2003). http://dx.doi.org/10.1021/la0264670
  3. A. K. Axelsson and L. J. Dunne, J. Photochem. Photobiol. A: Chem. 144, 205 (2001). http://dx.doi.org/10.1016/S1010-6030(01)00536-6
  4. J. Yu, J. C. Yu, M. K. P. Leung, W. Ho, B. Cheng, X. Zhao and J. Zhao, J. Catal. 217, 69 (2007).
  5. N. Q. Wu, J. Wang, D. N. Tafen, H. Wang and J. G. Zheng, J. Am. Chem. Soc. 132, 6679 (2010). http://dx.doi.org/10.1021/ja909456f
  6. A. Mills, A. Lepre, N. Elliott, S. Bhopal, I. P. Parkin and S. A. O’Neill, J. Photochem. Photobiol. A 160, 213 (2003). http://dx.doi.org/10.1016/S1010-6030(03)00205-3
  7. H. J. Liu, G. G. Liu and X. Y. Shi, Colloids and Surfaces A: Physicochem. Eng. Aspects 363, 35 (2010). http://dx.doi.org/10.1016/j.colsurfa.2010.04.010
  8. R. Erwin, J. P. Daniel and C. Christine, J. Am. Chem. Soc. 131, 18457 (2009). http://dx.doi.org/10.1021/ja907923r
  9. J. G. Yu, J. Yu and J. Zhao, Appl. Catal. B: Environ. 36, 31 (2002). http://dx.doi.org/10.1016/S0926-3373(01)00277-6
  10. C. Natalia, S. Fernando and E. García, J. Phys. Chem. C 112, 1094 (2008). http://dx.doi.org/10.1021/jp0769781
  11. M. Anpo, M. Takeuchi, K. Ikeue and S. Dohshi, Curr. Opin. Solid State Mater. Sci. 6, 381 (2002). http://dx.doi.org/10.1016/S1359-0286(02)00107-9
  12. H. Kisch, L. Zang, C. Lange, W. F. Maier, C. Antonius and D. Meissner, Angew. Chem. Int. Ed. 37, 3034 (1998). http://dx.doi.org/10.1002/(SICI)1521-3773(19981116)37:21$<$3034::AID-ANIE3034$>$3.0.CO;2-2
  13. T. Umebayashi, T. Yamaki, H. Itoh and K. Asai, Appl. Phys. Lett. 81, 454 (2002). http://dx.doi.org/10.1063/1.1493647
  14. R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki and Y. Taga, Science 293, 269 (2001). http://dx.doi.org/10.1126/science.1061051
  15. Y. Yang, X. J. Li, J. T. Chen, L. Y. Wang, J. Photochem. Photobiol. A: Chem. 163, 517 (2004). http://dx.doi.org/10.1016/j.jphotochem.2004.02.008
  16. B. Sun, E. P. Reddy and P. G. Smirniotis, Appl. Catal. B: Environ. 57, 139 (2005). http://dx.doi.org/10.1016/j.apcatb.2004.10.016
  17. E. V. Alexei, F. Yutaka, X. T. Zhang, M. Jin, M. Taketoshi and F. Akira, J. Phys. Chem. B 109, 24441 (2005). http://dx.doi.org/10.1021/jp055090e
  18. S. F. Chen and G. Y. Cao, Desalination 194, 127 (2006). http://dx.doi.org/10.1016/j.desal.2005.11.006
  19. C. Y. Wang, C. Bottcher, D. W. Bahnemann and J. K. Dohrmann, J. Mater. Chem. 13, 2322 (2003). http://dx.doi.org/10.1039/b303716a
  20. P. Kopf, E. Gilbert and S. H. Eberle, J. Photochem. Photobiol. A: Chem. 136, 163 (2000). http://dx.doi.org/10.1016/S1010-6030(00)00331-2
  21. A. Sclafani, L. Palmisano and E. J. Davi, Photochem. Photobiol. A: Chem. 56, 113 (1991).
  22. Y. M. Xu and H. Q. Lu, J. Photochem. Photobiol. A: Chem. 136, 73 (2000). http://dx.doi.org/10.1016/S1010-6030(00)00310-5
Read More
Author biographies are not available.
Download this PDF file
PDF
Statistic
Read Counter : 3927 Download : 2988

Most read articles by the same author(s)

<< < 1 2