Silver Nanowire Electrodes: Conductivity Improvement Without Post-treatment and Application in Capacitive Pressure Sensors
Corresponding Author: Peng He
Nano-Micro Letters,
Vol. 7 No. 1 (2015), Article Number: 51-58
Abstract
Transparent electrode based on silver nanowires (AgNWs) emerges as an outstanding alternative of indium tin oxide film especially for flexible electronics. However, the conductivity of AgNWs transparent electrode is still dramatically limited by the contact resistance between nanowires at high transmittance. Polyvinylpyrrolidone (PVP) layer adsorbed on the nanowire surface acts as an electrically insulating barrier at wire–wire junctions, and some devastating post-treatment methods are proposed to reduce or eliminate PVP layer, which usually limit the application of the substrates susceptible to heat or pressure and burden the fabrication with high-cost, time-consuming, or inefficient processes. In this work, a simple and rapid pre-treatment washing method was proposed to reduce the thickness of PVP layer from 13.19 to 0.96 nm and improve the contact between wires. AgNW electrodes with sheet resistances of 15.6 and 204 Ω sq−1 have been achieved at transmittances of 90 and 97.5 %, respectively. This method avoided any post-treatments and popularized the application of high-performance AgNW transparent electrode on more substrates. The improved AgNWs were successfully employed in a capacitive pressure sensor with high transparency, sensitivity, and reproducibility.
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- X. Li, D. Zhang, S. Chen, H. Zhang, Z. Sun, S. Huang, X. Yin, Dye-sensitized solar cells with higher Jsc by using polyvinylidene fluoride membrane counter electrodes. Nano-Micro Lett. 3(3), 195–199 (2011). doi:10.3786/nml.v3i3.p195-199
- Y.H. Kim, J. Lee, S. Hofmann, M.C. Gather, L. Müller-Meskamp, K. Leo, Achieving high efficiency and improved stability in ITO-free transparent organic light-emitting diodes with conductive polymer electrodes. Adv. Funct. Mater. 23(30), 3763–3769 (2013). doi:10.1002/adfm.201203449
- J. Lee, P. Lee, H.B. Lee, S. Hong, I. Lee, J. Yeo, S.S. Lee, T.S. Kim, D. Lee, S.H. Ko, Room-temperature nanosoldering of a very long metal nanowire network by conducting-polymer-assisted joining for a flexible touch-panel application. Adv. Funct. Mater. 23(34), 4171–4176 (2013). doi:10.1002/adfm.201203802
- W. Hu, X. Niu, R. Zhao, Q. Pei, Elastomeric transparent capacitive sensors based on an interpenetrating composite of silver nanowires and polyurethane. Appl. Phys. Lett. 102(8), 083303 (2013). doi:10.1063/1.4794143
- D.S. Hecht, L. Hu, G. Irvin, Emerging transparent electrodes based on thin films of carbon nanotubes, graphene, and metallic nanostructures. Adv. Mater. 23(13), 1482–1513 (2011). doi:10.1002/adma.201003188
- Y. Zhi, G. Rungang, H. Nantao, C. Jing, C. Yingwu, Z. Liying, W. Hao, K. Eric Siu-Wai, Z. Yafei, The prospective 2D graphene nanosheets: preparation, functionalization and applications. Nano-Micro Lett. 4(1), 1–9 (2012). doi:10.3786/nml.v4i1.p1-9
- J.G. Tait, B.J. Worfolk, S.A. Maloney, T.C. Hauger, A.L. Elias, J.M. Buriak, K.D. Harris, Spray coated high-conductivity PEDOT: PSS transparent electrodes for stretchable and mechanically-robust organic solar cells. Sol. Energy Mater. Sol. Cells 110, 98–106 (2013). doi:10.1016/j.solmat.2012.09.005
- T. Tokuno, M. Nogi, J. Jiu, T. Sugahara, K. Suganuma, Transparent electrodes fabricated via the self-assembly of silver nanowires using a bubble template. Langmuir 28(25), 9298–9302 (2012). doi:10.1021/la300961m
- M. Liu, Z. Wu, W.M. Lau, J. Yang, Recent advances in directed assembly of nanowires or nanotubes. Nano-Micro Lett. 4(3), 142–153 (2012). doi:10.3786/nml.v4i3.p142-153
- L. Yang, T. Zhang, H. Zhou, S.C. Price, B.J. Wiley, W. You, Solution-processed flexible polymer solar cells with silver nanowire electrodes. ACS Appl. Mater. Interfaces 3(10), 4075–4084 (2011). doi:10.1021/am2009585
- L. Daniel, G. Gaël, M. Céline, C. Caroline, B. Daniel, S. Jean-Pierre, Flexible transparent conductive materials based on silver nanowire networks: a review. Nanotechnology 24(45), 452001 (2013). doi:10.1088/0957-4484/24/45/452001
- J. Jiu, T. Araki, J. Wang, M. Nogi, T. Sugahara, S. Nagao, H. Koga, K. Suganuma, E. Nakazawa, M. Hara, H. Uchida, K. Shinozaki, Facile synthesis of very-long silver nanowires for transparent electrodes. J. Mater. Chem. A 2(18), 6326–6330 (2014). doi:10.1039/c4ta00502c
- J. Jiu, T. Sugahara, M. Nogi, K. Suganuma, Ag nanowires: large-scale synthesis via a trace-salt-assisted solvothermal process and application in transparent electrodes. J. Nanopart. Res. 15(4), 1588 (2013). doi:10.1007/s11051-013-1588-3
- S. De, T.M. Higgins, P.E. Lyons, E.M. Doherty, P.N. Nirmalraj, W.J. Blau, J.J. Boland, J.N. Coleman, Silver nanowire networks as flexible, transparent, conducting films: extremely high DC to optical conductivity ratios. ACS Nano 3(7), 1767–1774 (2009). doi:10.1021/nn900348c
- J. Lee, I. Lee, T.S. Kim, J.Y. Lee, Efficient welding of silver nanowire networks without post-processing. Small 9, 2887–2894 (2013). doi:10.1002/smll.201203142
- T. Tokuno, M. Nogi, M. Karakawa, J. Jiu, T.T. Nge, Y. Aso, K. Suganuma, Fabrication of silver nanowire transparent electrodes at room temperature. Nano Res. 4(12), 1215–1222 (2011). doi:10.1007/s12274-011-0172-3
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- P.C. Hsu, S. Wang, H. Wu, V.K. Narasimhan, D. Kong, H.R. Lee, Y. Cui, Performance enhancement of metal nanowire transparent conducting electrodes by mesoscale metal wires. Nat. Commun. 4, 2522 (2013). doi:10.1038/ncomms3522
- L. Hu, H.S. Kim, J.-Y. Lee, P. Peumans, Y. Cui, Scalable coating and properties of transparent, flexible, silver nanowire electrodes. ACS Nano 4(5), 2955–2963 (2010). doi:10.1021/nn1005232
- P. Lee, J. Lee, H. Lee, J. Yeo, S. Hong, K.H. Nam, D. Lee, S.S. Lee, S.H. Ko, Highly stretchable and highly conductive metal electrode by very long metal nanowire percolation network. Adv. Mater. 24(25), 3326–3332 (2012). doi:10.1002/adma.201200359
- T. Araki, J. Jiu, M. Nogi, H. Koga, S. Nagao, T. Sugahara, K. Suganuma, Low haze transparent electrodes and highly conducting air dried films with ultra-long silver nanowires synthesized by one-step polyol method. Nano Res. 7(2), 236–245 (2014). doi:10.1007/s12274-013-0391-x
- P. Peng, A. Hu, H. Huang, A.P. Gerlich, B. Zhao, Y.N. Zhou, Room-temperature pressureless bonding with silver nanowire paste: towards organic electronic and heat-sensitive functional devices packaging. J. Mater. Chem. 22(26), 12997–13001 (2012). doi:10.1039/C2JM31979A
- Z. Zhang, B. Zhao, L. Hu, PVP protective mechanism of ultrafine silver powder synthesized by chemical reduction processes. J. Solid State Chem. 121(1), 105–110 (1996). doi:10.1006/jssc.1996.0015
- V. Bühler, Polyvinylpyrrolidone excipients for pharmaceuticals, vol. 2 (Springer, Berlin, 2005), pp. 5–124. doi:10.1007/3-540-27090-6_2
- S. De, J.N. Coleman, The effects of percolation in nanostructured transparent conductors. Mater. Res. Soc. Bull. 36(10), 774–781 (2011). doi:10.1557/mrs.2011.236
- J. Lee, P. Lee, H. Lee, D. Lee, S.S. Lee, S.H. Ko, Very long Ag nanowire synthesis and its application in a highly transparent, conductive and flexible metal electrode touch panel. Nanoscale 4(20), 6408–6414 (2012). doi:10.1039/c2nr31254a
- T.M. Barnes, M.O. Reese, J.D. Bergeson, B.A. Larsen, J.L. Blackburn, M.C. Beard, J. Bult, J. van de Lagemaat, Comparing the fundamental physics and device performance of transparent, conductive nanostructured networks with conventional transparent conducting oxides. Adv. Energy Mater. 2(3), 353–360 (2012). doi:10.1002/aenm.201100608
- S.H. David, M.H. Amy, L. Roland, H. Liangbing, M. Bryon, C. Chad, R. Steven, High conductivity transparent carbon nanotube films deposited from superacid. Nanotechnology 22(7), 075201 (2011). doi:10.1088/0957-4484/22/7/075201
- S. Bae, H. Kim, Y. Lee, X. Xu, J.S. Park, Y. Zheng, J. Balakrishnan, T. Lei, H. Ri Kim, Y.I. Song, Y.J. Kim, K.S. Kim, B. Ozyilmaz, J.H. Ahn, B.H. Hong, S. Iijima, Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nat. Nanotechnol. 5(8), 574–578 (2010). doi:10.1038/nnano.2010.132
- C. Mayousse, C. Celle, E. Moreau, J.F. Mainguet, A. Carella, J.P. Simonato, Improvements in purification of silver nanowires by decantation and fabrication of flexible transparent electrodes. Application to capacitive touch sensors. Nanotechnology 24(21), 215501 (2013). doi:10.1088/0957-4484/24/21/215501
References
X. Li, D. Zhang, S. Chen, H. Zhang, Z. Sun, S. Huang, X. Yin, Dye-sensitized solar cells with higher Jsc by using polyvinylidene fluoride membrane counter electrodes. Nano-Micro Lett. 3(3), 195–199 (2011). doi:10.3786/nml.v3i3.p195-199
Y.H. Kim, J. Lee, S. Hofmann, M.C. Gather, L. Müller-Meskamp, K. Leo, Achieving high efficiency and improved stability in ITO-free transparent organic light-emitting diodes with conductive polymer electrodes. Adv. Funct. Mater. 23(30), 3763–3769 (2013). doi:10.1002/adfm.201203449
J. Lee, P. Lee, H.B. Lee, S. Hong, I. Lee, J. Yeo, S.S. Lee, T.S. Kim, D. Lee, S.H. Ko, Room-temperature nanosoldering of a very long metal nanowire network by conducting-polymer-assisted joining for a flexible touch-panel application. Adv. Funct. Mater. 23(34), 4171–4176 (2013). doi:10.1002/adfm.201203802
W. Hu, X. Niu, R. Zhao, Q. Pei, Elastomeric transparent capacitive sensors based on an interpenetrating composite of silver nanowires and polyurethane. Appl. Phys. Lett. 102(8), 083303 (2013). doi:10.1063/1.4794143
D.S. Hecht, L. Hu, G. Irvin, Emerging transparent electrodes based on thin films of carbon nanotubes, graphene, and metallic nanostructures. Adv. Mater. 23(13), 1482–1513 (2011). doi:10.1002/adma.201003188
Y. Zhi, G. Rungang, H. Nantao, C. Jing, C. Yingwu, Z. Liying, W. Hao, K. Eric Siu-Wai, Z. Yafei, The prospective 2D graphene nanosheets: preparation, functionalization and applications. Nano-Micro Lett. 4(1), 1–9 (2012). doi:10.3786/nml.v4i1.p1-9
J.G. Tait, B.J. Worfolk, S.A. Maloney, T.C. Hauger, A.L. Elias, J.M. Buriak, K.D. Harris, Spray coated high-conductivity PEDOT: PSS transparent electrodes for stretchable and mechanically-robust organic solar cells. Sol. Energy Mater. Sol. Cells 110, 98–106 (2013). doi:10.1016/j.solmat.2012.09.005
T. Tokuno, M. Nogi, J. Jiu, T. Sugahara, K. Suganuma, Transparent electrodes fabricated via the self-assembly of silver nanowires using a bubble template. Langmuir 28(25), 9298–9302 (2012). doi:10.1021/la300961m
M. Liu, Z. Wu, W.M. Lau, J. Yang, Recent advances in directed assembly of nanowires or nanotubes. Nano-Micro Lett. 4(3), 142–153 (2012). doi:10.3786/nml.v4i3.p142-153
L. Yang, T. Zhang, H. Zhou, S.C. Price, B.J. Wiley, W. You, Solution-processed flexible polymer solar cells with silver nanowire electrodes. ACS Appl. Mater. Interfaces 3(10), 4075–4084 (2011). doi:10.1021/am2009585
L. Daniel, G. Gaël, M. Céline, C. Caroline, B. Daniel, S. Jean-Pierre, Flexible transparent conductive materials based on silver nanowire networks: a review. Nanotechnology 24(45), 452001 (2013). doi:10.1088/0957-4484/24/45/452001
J. Jiu, T. Araki, J. Wang, M. Nogi, T. Sugahara, S. Nagao, H. Koga, K. Suganuma, E. Nakazawa, M. Hara, H. Uchida, K. Shinozaki, Facile synthesis of very-long silver nanowires for transparent electrodes. J. Mater. Chem. A 2(18), 6326–6330 (2014). doi:10.1039/c4ta00502c
J. Jiu, T. Sugahara, M. Nogi, K. Suganuma, Ag nanowires: large-scale synthesis via a trace-salt-assisted solvothermal process and application in transparent electrodes. J. Nanopart. Res. 15(4), 1588 (2013). doi:10.1007/s11051-013-1588-3
S. De, T.M. Higgins, P.E. Lyons, E.M. Doherty, P.N. Nirmalraj, W.J. Blau, J.J. Boland, J.N. Coleman, Silver nanowire networks as flexible, transparent, conducting films: extremely high DC to optical conductivity ratios. ACS Nano 3(7), 1767–1774 (2009). doi:10.1021/nn900348c
J. Lee, I. Lee, T.S. Kim, J.Y. Lee, Efficient welding of silver nanowire networks without post-processing. Small 9, 2887–2894 (2013). doi:10.1002/smll.201203142
T. Tokuno, M. Nogi, M. Karakawa, J. Jiu, T.T. Nge, Y. Aso, K. Suganuma, Fabrication of silver nanowire transparent electrodes at room temperature. Nano Res. 4(12), 1215–1222 (2011). doi:10.1007/s12274-011-0172-3
J. Jiu, T. Sugahara, M. Nogi, T. Araki, K. Suganuma, H. Uchida, K. Shinozaki, High-intensity pulse light sintering of silver nanowire transparent films on polymer substrates: the effect of the thermal properties of substrates on the performance of silver films. Nanoscale 5(23), 11820–11828 (2013). doi:10.1039/c3nr03152g
P.C. Hsu, S. Wang, H. Wu, V.K. Narasimhan, D. Kong, H.R. Lee, Y. Cui, Performance enhancement of metal nanowire transparent conducting electrodes by mesoscale metal wires. Nat. Commun. 4, 2522 (2013). doi:10.1038/ncomms3522
L. Hu, H.S. Kim, J.-Y. Lee, P. Peumans, Y. Cui, Scalable coating and properties of transparent, flexible, silver nanowire electrodes. ACS Nano 4(5), 2955–2963 (2010). doi:10.1021/nn1005232
P. Lee, J. Lee, H. Lee, J. Yeo, S. Hong, K.H. Nam, D. Lee, S.S. Lee, S.H. Ko, Highly stretchable and highly conductive metal electrode by very long metal nanowire percolation network. Adv. Mater. 24(25), 3326–3332 (2012). doi:10.1002/adma.201200359
T. Araki, J. Jiu, M. Nogi, H. Koga, S. Nagao, T. Sugahara, K. Suganuma, Low haze transparent electrodes and highly conducting air dried films with ultra-long silver nanowires synthesized by one-step polyol method. Nano Res. 7(2), 236–245 (2014). doi:10.1007/s12274-013-0391-x
P. Peng, A. Hu, H. Huang, A.P. Gerlich, B. Zhao, Y.N. Zhou, Room-temperature pressureless bonding with silver nanowire paste: towards organic electronic and heat-sensitive functional devices packaging. J. Mater. Chem. 22(26), 12997–13001 (2012). doi:10.1039/C2JM31979A
Z. Zhang, B. Zhao, L. Hu, PVP protective mechanism of ultrafine silver powder synthesized by chemical reduction processes. J. Solid State Chem. 121(1), 105–110 (1996). doi:10.1006/jssc.1996.0015
V. Bühler, Polyvinylpyrrolidone excipients for pharmaceuticals, vol. 2 (Springer, Berlin, 2005), pp. 5–124. doi:10.1007/3-540-27090-6_2
S. De, J.N. Coleman, The effects of percolation in nanostructured transparent conductors. Mater. Res. Soc. Bull. 36(10), 774–781 (2011). doi:10.1557/mrs.2011.236
J. Lee, P. Lee, H. Lee, D. Lee, S.S. Lee, S.H. Ko, Very long Ag nanowire synthesis and its application in a highly transparent, conductive and flexible metal electrode touch panel. Nanoscale 4(20), 6408–6414 (2012). doi:10.1039/c2nr31254a
T.M. Barnes, M.O. Reese, J.D. Bergeson, B.A. Larsen, J.L. Blackburn, M.C. Beard, J. Bult, J. van de Lagemaat, Comparing the fundamental physics and device performance of transparent, conductive nanostructured networks with conventional transparent conducting oxides. Adv. Energy Mater. 2(3), 353–360 (2012). doi:10.1002/aenm.201100608
S.H. David, M.H. Amy, L. Roland, H. Liangbing, M. Bryon, C. Chad, R. Steven, High conductivity transparent carbon nanotube films deposited from superacid. Nanotechnology 22(7), 075201 (2011). doi:10.1088/0957-4484/22/7/075201
S. Bae, H. Kim, Y. Lee, X. Xu, J.S. Park, Y. Zheng, J. Balakrishnan, T. Lei, H. Ri Kim, Y.I. Song, Y.J. Kim, K.S. Kim, B. Ozyilmaz, J.H. Ahn, B.H. Hong, S. Iijima, Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nat. Nanotechnol. 5(8), 574–578 (2010). doi:10.1038/nnano.2010.132
C. Mayousse, C. Celle, E. Moreau, J.F. Mainguet, A. Carella, J.P. Simonato, Improvements in purification of silver nanowires by decantation and fabrication of flexible transparent electrodes. Application to capacitive touch sensors. Nanotechnology 24(21), 215501 (2013). doi:10.1088/0957-4484/24/21/215501