Issue

Vol. 15 (2023)

Intrinsic Self-Healing Chemistry for Next-Generation Flexible Energy Storage Devices

https://doi.org/10.1007/s40820-023-01075-9
Xin Wan
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Tiansheng Mu
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Geping Yin
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China

Corresponding Author: Geping Yin

yingeping@hit.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 99

Abstract

The booming wearable/portable electronic devices industry has stimulated the progress of supporting flexible energy storage devices. Excellent performance of flexible devices not only requires the component units of each device to maintain the original performance under external forces, but also demands the overall device to be flexible in response to external fields. However, flexible energy storage devices inevitably occur mechanical damages (extrusion, impact, vibration)/electrical damages (overcharge, over-discharge, external short circuit) during long-term complex deformation conditions, causing serious performance degradation and safety risks. Inspired by the healing phenomenon of nature, endowing energy storage devices with self-healing capability has become a promising strategy to effectively improve the durability and functionality of devices. Herein, this review systematically summarizes the latest progress in intrinsic self-healing chemistry for energy storage devices. Firstly, the main intrinsic self-healing mechanism is introduced. Then, the research situation of electrodes, electrolytes, artificial interface layers and integrated devices based on intrinsic self-healing and advanced characterization technology is reviewed. Finally, the current challenges and perspective are provided. We believe this critical review will contribute to the development of intrinsic self-healing chemistry in the flexible energy storage field.


Highlights:


1 The introduction of self-healing mechanism into flexible energy storage devices is expected to solve the problems of mechanical and electrochemical performance degradation caused by mechanical deformation.
2 Applications of different healing mechanisms and advanced characterization techniques in energy storage devices are summarized.
3 The key challenges of self-healing in the field of flexible energy storage are pointed out, and the future research direction is prospected.

Keywords

Flexible energy storage Intrinsic self-healing chemistry Lithium-ion battery Supercapacitor Advanced characterizations
Wan, Xin, Tiansheng Mu, and Geping Yin. 2023. “Intrinsic Self-Healing Chemistry for Next-Generation Flexible Energy Storage Devices”. Nano-Micro Letters 15 (April):99. https://doi.org/10.1007/s40820-023-01075-9.
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